Isolation and spectroscopic characterisation of C60F18CF2, the first difluoromethano 60 fullerene
Isolation and spectroscopic characterisation of C60F18CF2, the first difluoromethano 60 fullerene
From the fluorination of [60]fullerene by K2PtF6 at 465 degrees C under 0.1 bar, we have isolated and characterised C60F18CF2 which has C-s symmetry and is isostructural with C60F18O; it co-elutes (HPLC) with a minor unsymmetrical isomer.
adducts, c-60
1-3
Avent, A. G.
bd34ffe6-fea1-4e75-81fc-82ecaa0c0b5a
Boltalina, O. V.
c91e33b3-7da7-4481-95f4-92fce2a56e46
Lukonin, A. Y.
758144bd-dfdd-42fa-bf14-c73bf69e8f53
Street, J. M.
67b5e419-1784-425f-a913-f67d1fae8b22
Taylor, R.
1abcd415-ae2c-4e95-a761-6948ce7f4d32
1 January 2000
Avent, A. G.
bd34ffe6-fea1-4e75-81fc-82ecaa0c0b5a
Boltalina, O. V.
c91e33b3-7da7-4481-95f4-92fce2a56e46
Lukonin, A. Y.
758144bd-dfdd-42fa-bf14-c73bf69e8f53
Street, J. M.
67b5e419-1784-425f-a913-f67d1fae8b22
Taylor, R.
1abcd415-ae2c-4e95-a761-6948ce7f4d32
Avent, A. G., Boltalina, O. V., Lukonin, A. Y., Street, J. M. and Taylor, R.
(2000)
Isolation and spectroscopic characterisation of C60F18CF2, the first difluoromethano 60 fullerene.
Journal of the Chemical Society, Perkin Transactions 2, (1), .
(doi:10.1039/a909157b).
Abstract
From the fluorination of [60]fullerene by K2PtF6 at 465 degrees C under 0.1 bar, we have isolated and characterised C60F18CF2 which has C-s symmetry and is isostructural with C60F18O; it co-elutes (HPLC) with a minor unsymmetrical isomer.
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Published date: 1 January 2000
Keywords:
adducts, c-60
Identifiers
Local EPrints ID: 18989
URI: http://eprints.soton.ac.uk/id/eprint/18989
PURE UUID: c1c0cb79-0957-4c05-a842-6911343772ad
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Date deposited: 21 Dec 2005
Last modified: 15 Mar 2024 06:09
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Contributors
Author:
A. G. Avent
Author:
O. V. Boltalina
Author:
A. Y. Lukonin
Author:
J. M. Street
Author:
R. Taylor
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