An Investigation of the Factors that Influence the Decomposition of 7,7',8,8'-Tetracyanoquinodimethane (TCNQ) and Its Salts to, and Structural Characterization of, the ?,?-Dicyano-p-toluoylcyanide Anion
An Investigation of the Factors that Influence the Decomposition of 7,7',8,8'-Tetracyanoquinodimethane (TCNQ) and Its Salts to, and Structural Characterization of, the ?,?-Dicyano-p-toluoylcyanide Anion
The kinetics of formation of alpha,alpha-dicyano-p-toluoylcyanide anion (DCTC-) by reaction of TCNQ(0) and its radical anion salts with nitrite ion have been investigated spectroscopically; the reaction of TCNQ(0) with excess nitrite is first order, whereas oxidation of TCNQ(.-) appears to proceed via TCNQ(0) as an intermediate. The first X-ray structural study of a simple DCTC- salt, K+[2.2.2] DCTC-, is also reported.
tetracyanoquinodimethane, raman
2319-2323
Grossel, M. C.
d5538798-b179-4aca-a755-567cf9d1ca65
Duke, A. J.
62e171f7-4872-455e-8263-35ff7ba0c9fe
Hibbert, D. B.
1b2731ec-0b10-4025-87a3-f8b906d31034
Lewis, I. K.
12ce596f-6d2b-447e-9415-7870881678a8
Seddon, E. A.
5aa91a9f-ca16-43e0-8990-e76ad42bf503
Horton, P. N.
af4b0204-e529-454f-b74a-f5198786ce67
Weston, S. C.
f269e7fc-190d-418e-816c-5fb1fc231659
1 August 2000
Grossel, M. C.
d5538798-b179-4aca-a755-567cf9d1ca65
Duke, A. J.
62e171f7-4872-455e-8263-35ff7ba0c9fe
Hibbert, D. B.
1b2731ec-0b10-4025-87a3-f8b906d31034
Lewis, I. K.
12ce596f-6d2b-447e-9415-7870881678a8
Seddon, E. A.
5aa91a9f-ca16-43e0-8990-e76ad42bf503
Horton, P. N.
af4b0204-e529-454f-b74a-f5198786ce67
Weston, S. C.
f269e7fc-190d-418e-816c-5fb1fc231659
Grossel, M. C., Duke, A. J., Hibbert, D. B., Lewis, I. K., Seddon, E. A., Horton, P. N. and Weston, S. C.
(2000)
An Investigation of the Factors that Influence the Decomposition of 7,7',8,8'-Tetracyanoquinodimethane (TCNQ) and Its Salts to, and Structural Characterization of, the ?,?-Dicyano-p-toluoylcyanide Anion.
Chemistry of Materials, 12 (8), .
(doi:10.1021/cm991160g).
Abstract
The kinetics of formation of alpha,alpha-dicyano-p-toluoylcyanide anion (DCTC-) by reaction of TCNQ(0) and its radical anion salts with nitrite ion have been investigated spectroscopically; the reaction of TCNQ(0) with excess nitrite is first order, whereas oxidation of TCNQ(.-) appears to proceed via TCNQ(0) as an intermediate. The first X-ray structural study of a simple DCTC- salt, K+[2.2.2] DCTC-, is also reported.
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Published date: 1 August 2000
Keywords:
tetracyanoquinodimethane, raman
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Local EPrints ID: 18995
URI: http://eprints.soton.ac.uk/id/eprint/18995
ISSN: 0897-4756
PURE UUID: 06c1d327-5d44-4fdd-9369-f643053f05ca
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Date deposited: 17 Jan 2006
Last modified: 15 Mar 2024 06:09
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Author:
M. C. Grossel
Author:
A. J. Duke
Author:
D. B. Hibbert
Author:
I. K. Lewis
Author:
E. A. Seddon
Author:
P. N. Horton
Author:
S. C. Weston
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