Insertion of metallated epoxides into zirconacycles

Kasatkin, A. N. and Whitby, R. J. (2000) Insertion of metallated epoxides into zirconacycles Tetrahedron Letters, 41, (27), pp. 5275-5280. (doi:10.1016/S0040-4039(00)00805-4).


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Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert efficiently into zirconacycles via a 1,2-metallate rearrangement to form intermediates which eliminate Cp2Zr(R)O- to afford substituted alkenes.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/S0040-4039(00)00805-4
ISSNs: 0040-4039 (print)
Keywords: zirconium, zirconacycles, silicon, nitriles, carbenoids, alkenes tandem insertion, lithium chloroallylide, substituted epoxides, zirconium chemistry, oxiranyl anions, aldehydes, reagents, ketones, lithiation, alkynes
ePrint ID: 19000
Date :
Date Event
1 July 2000Published
Date Deposited: 15 Dec 2005
Last Modified: 16 Apr 2017 23:07
Further Information:Google Scholar

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