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?(2)-Sulfenamido complexes of uranium

Danopoulos, A. A., Hankin, D. M., Cafferkey, S. M. and Hursthouse, M. B. (2000) ?(2)-Sulfenamido complexes of uranium Journal of the Chemical Society Dalton Transactions, (10), pp. 1613-1615. (doi:10.1039/b000304m).

Record type: Article


Thermally stable ?(2)-sulfenamido complexes of uranium, U(?(2)-(BuNSPh)-N-t)(4) 1 and UCp2*(?(2)-(BuNSPh)-N-t)X, X=Cl 2a or Br 2b, have been prepared by metathetical reactions of LiN(Bu-t)SPh with UCl4/PMe3 and UCp2*Cl-2, respectively; 2 resists further substitution. Structure determination by X-ray diffraction shows that the bonding of the sulfenamido ligand is analogous to that found in its complexes with the early transition metals Ti, Zr, Mo and W. Indeed 1 is closely isostructural with the homoleptic zirconium complex, and 2a, 2b are effectively isostructural with ZrCp2(?(2)-(BuNSPh)-N-t)X.

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Published date: 2000
Keywords: crystal-structures, zirconium, titanium


Local EPrints ID: 19026
ISSN: 1472-7773
PURE UUID: ae191408-d33d-4b2b-b776-79d25b1aae20

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Date deposited: 20 Dec 2005
Last modified: 17 Jul 2017 16:34

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Author: A. A. Danopoulos
Author: D. M. Hankin
Author: S. M. Cafferkey
Author: M. B. Hursthouse

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