The electrosynthesis of diaryliodonium salts
The electrosynthesis of diaryliodonium salts
A simple, one-step procedure for the synthesis of diaryliodonium salts is described. It is shown that the electrochemical oxidation of an aryl iodide at a carbon felt anode in acetic acid/25% acetic anhydride/5% sulfuric acid in the presence of an arene leads to a diaryliodonium salt in good yield. The method allows the preparation of unsymmetrical, as well as symmetrical diaryliodonium salts.
iodine compounds
8995-8998
Peacock, M. J.
e8c55bb0-b31a-45f5-894f-15375bdfa1de
Pletcher, D.
8f934180-8464-46d8-a79b-6e89fe693bad
11 November 2000
Peacock, M. J.
e8c55bb0-b31a-45f5-894f-15375bdfa1de
Pletcher, D.
8f934180-8464-46d8-a79b-6e89fe693bad
Abstract
A simple, one-step procedure for the synthesis of diaryliodonium salts is described. It is shown that the electrochemical oxidation of an aryl iodide at a carbon felt anode in acetic acid/25% acetic anhydride/5% sulfuric acid in the presence of an arene leads to a diaryliodonium salt in good yield. The method allows the preparation of unsymmetrical, as well as symmetrical diaryliodonium salts.
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Published date: 11 November 2000
Keywords:
iodine compounds
Identifiers
Local EPrints ID: 19029
URI: http://eprints.soton.ac.uk/id/eprint/19029
ISSN: 0040-4039
PURE UUID: 17f1e691-4570-4968-9772-7cde68690234
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Date deposited: 15 Dec 2005
Last modified: 15 Mar 2024 06:10
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Author:
M. J. Peacock
Author:
D. Pletcher
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