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Acetoacetoxy ethyl methacrylate (AAEM) resin, a new scavenger for primary amines in the presence of secondary amines

Yu, Z. R., Alesso, S., Pears, D., Worthington, P. A., Luke, R. W. A. and Bradley, M. (2000) Acetoacetoxy ethyl methacrylate (AAEM) resin, a new scavenger for primary amines in the presence of secondary amines Tetrahedron Letters, 41, (46), pp. 8963-8967. (doi:10.1016/S0040-4039(00)01590-2).

Record type: Article

Abstract

Preliminary results on a new type of polymer scavenger, acetoacetoxy ethyl methacrylate (AAEM) resin, are reported. AAEM resin can selectively remove primary amines in the presence of secondary amines. Its application in a solution library synthesis is demonstrated.

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Published date: 11 November 2000
Keywords: combinatorial chemistry, reductive alkylation, polymer scavenger, amines small-molecule libraries, reductive amination, sodiumtriacetoxyborohydride, chemoselective reductions, solution-phase, purification, ketones, aldehydes, borohydride, reagents

Identifiers

Local EPrints ID: 19075
URI: http://eprints.soton.ac.uk/id/eprint/19075
ISSN: 0040-4039
PURE UUID: 11046c7b-b997-48f8-ab0c-9e511008ec46

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Date deposited: 15 Dec 2005
Last modified: 17 Jul 2017 16:33

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Contributors

Author: Z. R. Yu
Author: S. Alesso
Author: D. Pears
Author: P. A. Worthington
Author: R. W. A. Luke
Author: M. Bradley

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