7-(2'-Deoxy-?-D-ribofuranosyl)hypoxanthine
7-(2'-Deoxy-?-D-ribofuranosyl)hypoxanthine
The [alpha]-configured N7 analogue of 2'-deoxyinosine [7-(2'-deoxy-[alpha]-D-ribofuranosyl)hypoxanthine, C10H12N4O4] shows the following structural characteristics: (i) the furanose part of the molecule adopts the 2'-endo conformation [pseudorotation phase angle 166.4 (2)°]; (ii) the torsion angle [chi] (O4'-C1'-N7-C5) is syn [70.9 (1)°] with the base substituent pointing away from the sugar unit; (iii) the nucleobases are not hydrogen bonded to each other; only sugar-base hydrogen bonds between adjacent molecules were detected.
713-716
Marfurt, J.
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Stulz, E.
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Trafelet, H.U.
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Zingg, A.
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Leumann, C.
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Hazenkamp, M.
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Judd, R.
46480624-cff9-47d5-9cfa-64bedb8b9545
Schenker, S.
72641d7a-9a25-40ba-b545-3daab38ad754
Strouse, G.
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Ward, T.R.
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Förtsch, M.
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Hauser, J.
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Bürgi, H.B.
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March 1996
Marfurt, J.
d578a407-8b43-43b7-93fe-88e2a3874845
Stulz, E.
9a6c04cf-32ca-442b-9281-bbf3d23c622d
Trafelet, H.U.
919ac95d-401b-43a1-9ea1-df1aa75a29af
Zingg, A.
62cec465-75b8-4b11-9df3-14cd573cab63
Leumann, C.
0c05b292-039b-4fa6-84ff-182e71051ec3
Hazenkamp, M.
9432bb31-42f5-4602-835c-839019a94af9
Judd, R.
46480624-cff9-47d5-9cfa-64bedb8b9545
Schenker, S.
72641d7a-9a25-40ba-b545-3daab38ad754
Strouse, G.
a5a41178-0deb-44c3-b475-d391525053ec
Ward, T.R.
aaf7ac3a-21da-41bd-9498-073b78e706a9
Förtsch, M.
e1216888-c7a5-4677-934c-a63bee094dd6
Hauser, J.
e0748095-3f64-4d68-ae10-4c4c2f9bf8f1
Bürgi, H.B.
a6fb03f7-8f83-4e68-8c6d-1ee1ec2f123a
Marfurt, J., Stulz, E., Trafelet, H.U., Zingg, A., Leumann, C., Hazenkamp, M., Judd, R., Schenker, S., Strouse, G., Ward, T.R., Förtsch, M., Hauser, J. and Bürgi, H.B.
(1996)
7-(2'-Deoxy-?-D-ribofuranosyl)hypoxanthine.
Acta Crystallographica Section C: Crystal Structure Communications, 52 (3), .
(doi:10.1107/S0108270195012662).
Abstract
The [alpha]-configured N7 analogue of 2'-deoxyinosine [7-(2'-deoxy-[alpha]-D-ribofuranosyl)hypoxanthine, C10H12N4O4] shows the following structural characteristics: (i) the furanose part of the molecule adopts the 2'-endo conformation [pseudorotation phase angle 166.4 (2)°]; (ii) the torsion angle [chi] (O4'-C1'-N7-C5) is syn [70.9 (1)°] with the base substituent pointing away from the sugar unit; (iii) the nucleobases are not hydrogen bonded to each other; only sugar-base hydrogen bonds between adjacent molecules were detected.
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Published date: March 1996
Identifiers
Local EPrints ID: 191669
URI: http://eprints.soton.ac.uk/id/eprint/191669
ISSN: 0108-2701
PURE UUID: aa55a679-f449-435c-80b8-280227e60d58
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Date deposited: 23 Jun 2011 13:01
Last modified: 15 Mar 2024 03:26
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Contributors
Author:
J. Marfurt
Author:
H.U. Trafelet
Author:
A. Zingg
Author:
C. Leumann
Author:
M. Hazenkamp
Author:
R. Judd
Author:
S. Schenker
Author:
G. Strouse
Author:
T.R. Ward
Author:
M. Förtsch
Author:
J. Hauser
Author:
H.B. Bürgi
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