X-Ray structure and solvolytic activity towards phosphate diesters of a zirconium(IV) complex
X-Ray structure and solvolytic activity towards phosphate diesters of a zirconium(IV) complex
The X-ray structure of the complex Zr-IV(acac)(2)(salicylideneaminoethanol) [Zr(acac)(2)(sae)] could be solved, and the reactivity of the complex towards phosphate diester solvolysis was investigated showing substantial rate acceleration over background in benzene-methanol solution (ca. 10(8)) and in aqueous medium (ca. 10(5)).
239-240
Stulz, Eugen
9a6c04cf-32ca-442b-9281-bbf3d23c622d
Leumann, Christian
249e7dd9-7845-4a6c-ac0f-7fa09b0da4ad
1 January 1999
Stulz, Eugen
9a6c04cf-32ca-442b-9281-bbf3d23c622d
Leumann, Christian
249e7dd9-7845-4a6c-ac0f-7fa09b0da4ad
Stulz, Eugen and Leumann, Christian
(1999)
X-Ray structure and solvolytic activity towards phosphate diesters of a zirconium(IV) complex.
Chemical Communications, (3), .
(doi:10.1039/a809101c).
Abstract
The X-ray structure of the complex Zr-IV(acac)(2)(salicylideneaminoethanol) [Zr(acac)(2)(sae)] could be solved, and the reactivity of the complex towards phosphate diester solvolysis was investigated showing substantial rate acceleration over background in benzene-methanol solution (ca. 10(8)) and in aqueous medium (ca. 10(5)).
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Published date: 1 January 1999
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Local EPrints ID: 191673
URI: http://eprints.soton.ac.uk/id/eprint/191673
ISSN: 1359-7345
PURE UUID: b1fa178d-c727-462b-9ba9-e232352f029e
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Date deposited: 23 Jun 2011 13:05
Last modified: 15 Mar 2024 03:26
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Author:
Christian Leumann
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