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Phosphine-substituted porphyrins as supramolecular building blocks

Phosphine-substituted porphyrins as supramolecular building blocks
Phosphine-substituted porphyrins as supramolecular building blocks
A route to alkyne-phosphine-substituted metalloporphyrins is presented. The X-ray structure of the methanol adduct of a diphenylphosphine Zn(II) porphyrin reveals solid state dimerisation accompanied by proton transfer from coordinated methanol to phosphine in a process reminiscent of carbonic anhydrase, The ability of the phosphine-substituted porphyrins to form non-covalent arrays with a Ru(II) porphyrin was explored using H-1/P-31 NMR and UV/vis spectroscopy as well as MALDI-TOF mass spectrometry.
1144-0546
261-264
Darling, Scott L.
fbef4b54-4f6b-4528-adcd-987af79826e1
Stulz, Eugen
9a6c04cf-32ca-442b-9281-bbf3d23c622d
Feeder, Neil
f72b9f0c-f7a0-4d4a-9aa0-4654bd85c386
Bampos, Nick
a1d45344-d932-49c7-89ab-34ccd1d659aa
Sanders, Jeremy K.M.
a676d635-3196-437a-b894-a2bc5f857ae2
Darling, Scott L.
fbef4b54-4f6b-4528-adcd-987af79826e1
Stulz, Eugen
9a6c04cf-32ca-442b-9281-bbf3d23c622d
Feeder, Neil
f72b9f0c-f7a0-4d4a-9aa0-4654bd85c386
Bampos, Nick
a1d45344-d932-49c7-89ab-34ccd1d659aa
Sanders, Jeremy K.M.
a676d635-3196-437a-b894-a2bc5f857ae2

Darling, Scott L., Stulz, Eugen, Feeder, Neil, Bampos, Nick and Sanders, Jeremy K.M. (2000) Phosphine-substituted porphyrins as supramolecular building blocks. New Journal of Chemistry, 24 (5), 261-264. (doi:10.1039/b000482k).

Record type: Article

Abstract

A route to alkyne-phosphine-substituted metalloporphyrins is presented. The X-ray structure of the methanol adduct of a diphenylphosphine Zn(II) porphyrin reveals solid state dimerisation accompanied by proton transfer from coordinated methanol to phosphine in a process reminiscent of carbonic anhydrase, The ability of the phosphine-substituted porphyrins to form non-covalent arrays with a Ru(II) porphyrin was explored using H-1/P-31 NMR and UV/vis spectroscopy as well as MALDI-TOF mass spectrometry.

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Published date: 18 April 2000

Identifiers

Local EPrints ID: 191677
URI: http://eprints.soton.ac.uk/id/eprint/191677
ISSN: 1144-0546
PURE UUID: 86a2be11-99c7-4bb6-a285-ef7e9aed2d15
ORCID for Eugen Stulz: ORCID iD orcid.org/0000-0002-5302-2276

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Date deposited: 23 Jun 2011 12:59
Last modified: 10 Dec 2019 01:43

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