Heteronuclear tin(IV)-silver(I) complexes with phosphinothiolate ligands. X-ray structure of AgSn(mu-SC6H4PPh2)(2)Me-2(PPh2Me) CF3SO3 center dot CH2Cl2
Heteronuclear tin(IV)-silver(I) complexes with phosphinothiolate ligands. X-ray structure of AgSn(mu-SC6H4PPh2)(2)Me-2(PPh2Me) CF3SO3 center dot CH2Cl2
[SnR2(SC6H4PPh2)(2)] (R = Me or Ph) react with silver complexes such as [Ag(CF3SO3)(PR3)] (PR3 = PPh3 and PPh2Me) to give [AgSn(mu -SC6H4PPh2)(2)R-2(PR3)]CF3SO3 (1 - 4) where silver atom are co ordinated to the PPh2 group of the phosphinethiolate ligand as confirmed in the X-ray crystal structure of [AgSn(mu -SC6H4PPh2)(2)Me-2(PPh2Me)]CF3SO3. CH2Cl2 (2). Similar tin derivatives [SnR2{(SC6H4)(2)PPh}] (R = Me, 5; R = Ph, 6) where synthesised and reacted with [Ag(CF3SO3)(PR3)] and [Ag(CF3SO3)] to give in both cases [AgSn{mu-(C6H4)(2)PPh}R-2]CF3SO3 (R = Me, 7; R = Ph, 8)
tin, silver, phosphinethiolate, heteronuclear derivatives
carbon-monoxide dehydrogenase, coordination chemistry, clostridium-thermoaceticum, molecular-structures, crystal-structures, phosphorus, nickel, reactivity, protein
274-279
Aznar, J.
6f477675-ae49-4a0b-abc3-639b65ce3c62
Cerrada, E.
0eaa9f2b-2a66-4720-bf3d-c09e2f9da156
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Laguna, M.
2274f036-7200-4963-95ee-36d746d5238b
Pozo, C.
0809d875-8549-4b61-9832-c71c0dfa4139
Romero, M. P.
6334c3d2-7b21-4fb6-8005-3fb7e286fb01
15 March 2001
Aznar, J.
6f477675-ae49-4a0b-abc3-639b65ce3c62
Cerrada, E.
0eaa9f2b-2a66-4720-bf3d-c09e2f9da156
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Laguna, M.
2274f036-7200-4963-95ee-36d746d5238b
Pozo, C.
0809d875-8549-4b61-9832-c71c0dfa4139
Romero, M. P.
6334c3d2-7b21-4fb6-8005-3fb7e286fb01
Aznar, J., Cerrada, E., Hursthouse, M. B., Laguna, M., Pozo, C. and Romero, M. P.
(2001)
Heteronuclear tin(IV)-silver(I) complexes with phosphinothiolate ligands. X-ray structure of AgSn(mu-SC6H4PPh2)(2)Me-2(PPh2Me) CF3SO3 center dot CH2Cl2.
Journal of Organometallic Chemistry, 622 (1-2), .
(doi:10.1016/S0022-328X(00)00936-0).
Abstract
[SnR2(SC6H4PPh2)(2)] (R = Me or Ph) react with silver complexes such as [Ag(CF3SO3)(PR3)] (PR3 = PPh3 and PPh2Me) to give [AgSn(mu -SC6H4PPh2)(2)R-2(PR3)]CF3SO3 (1 - 4) where silver atom are co ordinated to the PPh2 group of the phosphinethiolate ligand as confirmed in the X-ray crystal structure of [AgSn(mu -SC6H4PPh2)(2)Me-2(PPh2Me)]CF3SO3. CH2Cl2 (2). Similar tin derivatives [SnR2{(SC6H4)(2)PPh}] (R = Me, 5; R = Ph, 6) where synthesised and reacted with [Ag(CF3SO3)(PR3)] and [Ag(CF3SO3)] to give in both cases [AgSn{mu-(C6H4)(2)PPh}R-2]CF3SO3 (R = Me, 7; R = Ph, 8)
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More information
Published date: 15 March 2001
Keywords:
tin, silver, phosphinethiolate, heteronuclear derivatives
carbon-monoxide dehydrogenase, coordination chemistry, clostridium-thermoaceticum, molecular-structures, crystal-structures, phosphorus, nickel, reactivity, protein
Identifiers
Local EPrints ID: 19388
URI: http://eprints.soton.ac.uk/id/eprint/19388
ISSN: 0022-328X
PURE UUID: 84c1d552-84d2-493f-8822-95212297b791
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Date deposited: 13 Feb 2006
Last modified: 15 Mar 2024 06:15
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Contributors
Author:
J. Aznar
Author:
E. Cerrada
Author:
M. Laguna
Author:
C. Pozo
Author:
M. P. Romero
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