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Solid-phase Friedel-Crafts acylation on polystyrene resins-synthesis of antiepiletic 1-aryl-3,5-dihydro-4H-2,3-benzodiazepin-4-ones

Solid-phase Friedel-Crafts acylation on polystyrene resins-synthesis of antiepiletic 1-aryl-3,5-dihydro-4H-2,3-benzodiazepin-4-ones
Solid-phase Friedel-Crafts acylation on polystyrene resins-synthesis of antiepiletic 1-aryl-3,5-dihydro-4H-2,3-benzodiazepin-4-ones
Friedel-Crafts acylation with various acyl chlorides of resin-bound 3,4-dimethoxyphenylacetate afforded resin bound ketones which, following treatment with hydrazine, were converted into the corresponding 2,3-benzodiazepines in good yields and purities.
solid-phase synthesis, friedel-crafts acylation, 2, 3-benzodiazepines ampa receptor antagonists
0040-4039
7683-7685
Bevacqua, F.
e085e2d2-dc9b-453c-95bc-82b756a32cca
Basso, A.
9cdcd616-ad0c-431a-b3f3-f39343a63694
Gitto, R.
25077a6b-6cdd-4ab9-8f46-e93bbcade1a1
Bradley, M.
078a34d6-96c4-4ce1-9aa1-454d9ee0030d
Chimirri, A.
13d96e18-f037-4f05-8941-a413f2114cb7
Bevacqua, F.
e085e2d2-dc9b-453c-95bc-82b756a32cca
Basso, A.
9cdcd616-ad0c-431a-b3f3-f39343a63694
Gitto, R.
25077a6b-6cdd-4ab9-8f46-e93bbcade1a1
Bradley, M.
078a34d6-96c4-4ce1-9aa1-454d9ee0030d
Chimirri, A.
13d96e18-f037-4f05-8941-a413f2114cb7

Bevacqua, F., Basso, A., Gitto, R., Bradley, M. and Chimirri, A. (2001) Solid-phase Friedel-Crafts acylation on polystyrene resins-synthesis of antiepiletic 1-aryl-3,5-dihydro-4H-2,3-benzodiazepin-4-ones. Tetrahedron Letters, 42 (43), 7683-7685. (doi:10.1016/S0040-4039(01)01602-1).

Record type: Article

Abstract

Friedel-Crafts acylation with various acyl chlorides of resin-bound 3,4-dimethoxyphenylacetate afforded resin bound ketones which, following treatment with hydrazine, were converted into the corresponding 2,3-benzodiazepines in good yields and purities.

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More information

Published date: 22 October 2001
Keywords: solid-phase synthesis, friedel-crafts acylation, 2, 3-benzodiazepines ampa receptor antagonists

Identifiers

Local EPrints ID: 19406
URI: http://eprints.soton.ac.uk/id/eprint/19406
ISSN: 0040-4039
PURE UUID: 6eaf2594-46a1-4544-89ce-6c7f18b3ceb1

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Date deposited: 14 Feb 2006
Last modified: 15 Mar 2024 06:15

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Contributors

Author: F. Bevacqua
Author: A. Basso
Author: R. Gitto
Author: M. Bradley
Author: A. Chimirri

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