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(2R,3S,4S,5R)-4-hydroxy-3-iodo-5-methyltetrahydro-2-furylmethyl benzoate

(2R,3S,4S,5R)-4-hydroxy-3-iodo-5-methyltetrahydro-2-furylmethyl benzoate
(2R,3S,4S,5R)-4-hydroxy-3-iodo-5-methyltetrahydro-2-furylmethyl benzoate
The crystal structure determination of the title compound, C13H15IO4, has allowed the relative stereochemistry between the tetrasubstituted C atoms on the tetrahydrofuran moiety to be confirmed. The title compound is a precursor of the ionophoric antibiotic Aplasmomycin. The compound is involved in both intra- and intermolecular hydrogen bonding, the latter link the molecules into chains running along the b axis.
(+)-aplasmomycin, aplasmomycin
o58-o60
Bew, S.P.
d58c5e68-9f12-42a4-8b86-9f443fca53e3
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Knight, D.W.
dbe05fb8-fea1-4e2e-8555-0c72c3f5bc65
Middleton, R.J.
2ff153e1-8c5f-4464-a16b-1e9181e95f2e
Bew, S.P.
d58c5e68-9f12-42a4-8b86-9f443fca53e3
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Knight, D.W.
dbe05fb8-fea1-4e2e-8555-0c72c3f5bc65
Middleton, R.J.
2ff153e1-8c5f-4464-a16b-1e9181e95f2e

Bew, S.P., Light, M.E., Hursthouse, M.B., Knight, D.W. and Middleton, R.J. (2001) (2R,3S,4S,5R)-4-hydroxy-3-iodo-5-methyltetrahydro-2-furylmethyl benzoate. Acta Crystallographica Section E: Structure Reports Online, E57, o58-o60.

Record type: Article

Abstract

The crystal structure determination of the title compound, C13H15IO4, has allowed the relative stereochemistry between the tetrasubstituted C atoms on the tetrahydrofuran moiety to be confirmed. The title compound is a precursor of the ionophoric antibiotic Aplasmomycin. The compound is involved in both intra- and intermolecular hydrogen bonding, the latter link the molecules into chains running along the b axis.

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More information

Published date: 1 January 2001
Keywords: (+)-aplasmomycin, aplasmomycin

Identifiers

Local EPrints ID: 19407
URI: http://eprints.soton.ac.uk/id/eprint/19407
PURE UUID: 8a8a4e43-1281-449b-ad15-afea4c6b37a8
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 06 Jun 2018 12:54

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