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meso-Octacyclopropylcalix[4]pyrrole ethanol solvate

meso-Octacyclopropylcalix[4]pyrrole ethanol solvate
meso-Octacyclopropylcalix[4]pyrrole ethanol solvate
The title compound, C44H52N4·C2H5OH, is a calix[4]pyrrole-type macrocycle acting as a receptor, by means of hydrogen-bond interactions to an ethanol solvent. The pyrrole groups are arranged in a 1,3-alternate conformation which gives rise to disorder in the ethanol guest, due to its ability to coordinate both above and below the plane of the macrocycle.
o258-o260
Camiolo, S.
20db6329-114d-41c4-8a2e-128c2b55fbd7
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gale, P.A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Paver, M.A.
1d01a98a-0b92-482a-8ee6-8909f57a2187
Camiolo, S.
20db6329-114d-41c4-8a2e-128c2b55fbd7
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gale, P.A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Paver, M.A.
1d01a98a-0b92-482a-8ee6-8909f57a2187

Camiolo, S., Coles, S.J., Gale, P.A., Hursthouse, M.B. and Paver, M.A. (2001) meso-Octacyclopropylcalix[4]pyrrole ethanol solvate. Acta Crystallographica Section E: Structure Reports Online, 57 (3), o258-o260. (doi:10.1107/S1600536801002719).

Record type: Article

Abstract

The title compound, C44H52N4·C2H5OH, is a calix[4]pyrrole-type macrocycle acting as a receptor, by means of hydrogen-bond interactions to an ethanol solvent. The pyrrole groups are arranged in a 1,3-alternate conformation which gives rise to disorder in the ethanol guest, due to its ability to coordinate both above and below the plane of the macrocycle.

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More information

Published date: 2001

Identifiers

Local EPrints ID: 19437
URI: https://eprints.soton.ac.uk/id/eprint/19437
PURE UUID: 27b08c4b-5220-40f2-bfaa-427474e1c2ed
ORCID for S.J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for P.A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 06 Jun 2018 12:54

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