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The effect of d-block metal complexation on the spectroscopic and redox properties of ferrocene derivatives containing pyridine ligands

The effect of d-block metal complexation on the spectroscopic and redox properties of ferrocene derivatives containing pyridine ligands
The effect of d-block metal complexation on the spectroscopic and redox properties of ferrocene derivatives containing pyridine ligands
Three ferrocene derivatives 1-3, each containing two pyridine ligands, form complexes with a variety of d-block metals, as evidenced by NMR and UV-vis spectroscopy and cyclic voltammetry. The X-ray crystal structures of 1 and its Mo(0) complex are reported. The Zn(II) and Cu(I) complexes of 1-3 have a 2/1 (ligand/metal) stoichiometry. The factors influencing the changes in the redox and chromogenic properties of these ligands upon complexation are discussed.
ferrocene, complexes, sensor, cyclic voltammetry, spectroscopy, crown-ether, unit, molecules, cryptands, metallocenes, platinum(ii), binuclear, centers, sensors
0022-328X
304-310
Carr, J.D.
d45dae95-cca7-4e63-8b78-e4d8abedc3f1
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Tucker, J.H.R.
51edde52-fe65-46d5-be36-0824dcda9e38
Carr, J.D.
d45dae95-cca7-4e63-8b78-e4d8abedc3f1
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Tucker, J.H.R.
51edde52-fe65-46d5-be36-0824dcda9e38

Carr, J.D., Coles, S.J., Hursthouse, M.B. and Tucker, J.H.R. (2001) The effect of d-block metal complexation on the spectroscopic and redox properties of ferrocene derivatives containing pyridine ligands. Journal of Organometallic Chemistry, 637-639, 304-310. (doi:10.1016/S0022-328X(01)00924-X).

Record type: Article

Abstract

Three ferrocene derivatives 1-3, each containing two pyridine ligands, form complexes with a variety of d-block metals, as evidenced by NMR and UV-vis spectroscopy and cyclic voltammetry. The X-ray crystal structures of 1 and its Mo(0) complex are reported. The Zn(II) and Cu(I) complexes of 1-3 have a 2/1 (ligand/metal) stoichiometry. The factors influencing the changes in the redox and chromogenic properties of these ligands upon complexation are discussed.

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More information

Published date: 3 December 2001
Keywords: ferrocene, complexes, sensor, cyclic voltammetry, spectroscopy, crown-ether, unit, molecules, cryptands, metallocenes, platinum(ii), binuclear, centers, sensors

Identifiers

Local EPrints ID: 19441
URI: http://eprints.soton.ac.uk/id/eprint/19441
ISSN: 0022-328X
PURE UUID: 3768ff80-9d09-4e51-83f2-1934d7bec17f
ORCID for S.J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 13 Feb 2006
Last modified: 19 Nov 2019 01:53

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