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mer-Bis{2,6-bis 1-(4-tert-butylphenylimino)ethyl -pyridine}zinc(II) bis tris(hexafluoroacetylacetonato)zincate(II) diethyl ether hemisolvate

Coles, S. J., Granifo, J., Hursthouse, M. B. and Osborne, A. G. (2001) mer-Bis{2,6-bis 1-(4-tert-butylphenylimino)ethyl -pyridine}zinc(II) bis tris(hexafluoroacetylacetonato)zincate(II) diethyl ether hemisolvate Acta Crystallographica Section E: Structure Reports Online, 57, (12), M535-M537. (doi:10.1107/S1600536801015458).

Record type: Article

Abstract

Reaction of [Zn(hfac)(2)]. 2H(2)O with L-1, where hfac and L-1 are hexafluoroacetylacetonate and 2,6-bis[1-(4-tert-butylphenylimino)ethyl]pyridine, respectively, results in the formation of [Zn(L-1)(2)][Zn(hfac)(3)](2), i.e. [Zn(C29H35N3)(2)][Zn(C5HF6O2)(3)](2). -0.5C(4)H(10)O. In the cation, the two L-1 ligands act as merterdentate ligands. Reaction of [Zn(hfac)(2)]. 2H(2)O with 2,2':6',2 " -terpyridine (terpy) results in the formation of [Zn(terpy)(2)](hfac)(2).

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More information

Published date: 1 November 2001
Keywords: molecular-structures, metal-ions, complexes

Identifiers

Local EPrints ID: 19452
URI: http://eprints.soton.ac.uk/id/eprint/19452
ISSN: 1600-5368
PURE UUID: 1fee1c40-d204-4cf3-b75e-7319d0208739
ORCID for S. J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 17 Jul 2017 16:31

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Contributors

Author: S. J. Coles ORCID iD
Author: J. Granifo
Author: A. G. Osborne

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