mer-Bis{2,6-bis 1-(4-tert-butylphenylimino)ethyl -pyridine}zinc(II) bis tris(hexafluoroacetylacetonato)zincate(II) diethyl ether hemisolvate
mer-Bis{2,6-bis 1-(4-tert-butylphenylimino)ethyl -pyridine}zinc(II) bis tris(hexafluoroacetylacetonato)zincate(II) diethyl ether hemisolvate
Reaction of [Zn(hfac)(2)]. 2H(2)O with L-1, where hfac and L-1 are hexafluoroacetylacetonate and 2,6-bis[1-(4-tert-butylphenylimino)ethyl]pyridine, respectively, results in the formation of [Zn(L-1)(2)][Zn(hfac)(3)](2), i.e. [Zn(C29H35N3)(2)][Zn(C5HF6O2)(3)](2). -0.5C(4)H(10)O. In the cation, the two L-1 ligands act as merterdentate ligands. Reaction of [Zn(hfac)(2)]. 2H(2)O with 2,2':6',2 " -terpyridine (terpy) results in the formation of [Zn(terpy)(2)](hfac)(2).
molecular-structures, metal-ions, complexes
M535-M537
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Granifo, J.
67754ecd-89bf-4736-aebd-0cb19f6f67d9
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Osborne, A. G.
9430fd91-c186-4b98-a713-74d9b6fbba4b
1 November 2001
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Granifo, J.
67754ecd-89bf-4736-aebd-0cb19f6f67d9
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Osborne, A. G.
9430fd91-c186-4b98-a713-74d9b6fbba4b
Coles, S. J., Granifo, J., Hursthouse, M. B. and Osborne, A. G.
(2001)
mer-Bis{2,6-bis 1-(4-tert-butylphenylimino)ethyl -pyridine}zinc(II) bis tris(hexafluoroacetylacetonato)zincate(II) diethyl ether hemisolvate.
Acta Crystallographica Section E Structure Reports Online, 57 (12), .
(doi:10.1107/S1600536801015458).
Abstract
Reaction of [Zn(hfac)(2)]. 2H(2)O with L-1, where hfac and L-1 are hexafluoroacetylacetonate and 2,6-bis[1-(4-tert-butylphenylimino)ethyl]pyridine, respectively, results in the formation of [Zn(L-1)(2)][Zn(hfac)(3)](2), i.e. [Zn(C29H35N3)(2)][Zn(C5HF6O2)(3)](2). -0.5C(4)H(10)O. In the cation, the two L-1 ligands act as merterdentate ligands. Reaction of [Zn(hfac)(2)]. 2H(2)O with 2,2':6',2 " -terpyridine (terpy) results in the formation of [Zn(terpy)(2)](hfac)(2).
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Published date: 1 November 2001
Keywords:
molecular-structures, metal-ions, complexes
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Local EPrints ID: 19452
URI: http://eprints.soton.ac.uk/id/eprint/19452
ISSN: 1600-5368
PURE UUID: 1fee1c40-d204-4cf3-b75e-7319d0208739
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Date deposited: 15 Feb 2006
Last modified: 12 Dec 2021 03:06
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Author:
J. Granifo
Author:
A. G. Osborne
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