(2S)-1-(4-Bromophenyl)-2-hydroxy-2- (2S,5R)-5-(1-hydroxy-1-methylethyl)- tetrahydrofuran-2-yl ethanone
(2S)-1-(4-Bromophenyl)-2-hydroxy-2- (2S,5R)-5-(1-hydroxy-1-methylethyl)- tetrahydrofuran-2-yl ethanone
The title compound, C15H19BrO4, was synthesized during studies on the oxidation of 1,5-dienes. The molecular structure exhibits R and S chiral centres at the 2- and 5- positions on the central tetrahydrofuran moiety, and an S centre at the hydroxyethanone pivot atom. Intermolecular hydrogen bonding gives rise to a one-dimensional-chain structure.
O1061-O1062
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
1 November 2001
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Coles, S. J. and Hursthouse, M. B.
(2001)
(2S)-1-(4-Bromophenyl)-2-hydroxy-2- (2S,5R)-5-(1-hydroxy-1-methylethyl)- tetrahydrofuran-2-yl ethanone.
Acta Crystallographica Section E: Structure Reports Online, 57 (11), .
(doi:10.1107/S1600536801017020).
Abstract
The title compound, C15H19BrO4, was synthesized during studies on the oxidation of 1,5-dienes. The molecular structure exhibits R and S chiral centres at the 2- and 5- positions on the central tetrahydrofuran moiety, and an S centre at the hydroxyethanone pivot atom. Intermolecular hydrogen bonding gives rise to a one-dimensional-chain structure.
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Published date: 1 November 2001
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Local EPrints ID: 19455
URI: http://eprints.soton.ac.uk/id/eprint/19455
PURE UUID: 6303dbb4-1b61-45aa-90dd-b2171949d075
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Date deposited: 15 Feb 2006
Last modified: 16 Mar 2024 03:05
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