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4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one

4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one
4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one
The title compound, C20H16O7, is an intermediate in the total synthesis of (+/-)-asarinin. The molecular structure contains four chiral centres and crystallizes as two independent molecules. The chirality of the two molecules is the same, but they adopt different conformations. The compound is enantiomeric, with the second enantiomer arising from the centrosymmetric nature of the space group.
o544-o546
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Coles, S. J. and Hursthouse, M. B. (2001) 4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one. Acta Crystallographica Section E: Structure Reports Online, 57 (6), o544-o546. (doi:10.1107/S1600536801007437).

Record type: Article

Abstract

The title compound, C20H16O7, is an intermediate in the total synthesis of (+/-)-asarinin. The molecular structure contains four chiral centres and crystallizes as two independent molecules. The chirality of the two molecules is the same, but they adopt different conformations. The compound is enantiomeric, with the second enantiomer arising from the centrosymmetric nature of the space group.

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More information

Published date: 1 June 2001

Identifiers

Local EPrints ID: 19456
URI: https://eprints.soton.ac.uk/id/eprint/19456
PURE UUID: 16b649e9-c4dc-4607-b6e2-08ad92976316
ORCID for S. J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 06 Jun 2018 12:54

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