4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one

Coles, S. J. and Hursthouse, M. B. (2001) 4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one Acta Crystallographica Section E: Structure Reports Online, 57, (6), o544-o546. (doi:10.1107/S1600536801007437).


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The title compound, C20H16O7, is an intermediate in the total synthesis of (+/-)-asarinin. The molecular structure contains four chiral centres and crystallizes as two independent molecules. The chirality of the two molecules is the same, but they adopt different conformations. The compound is enantiomeric, with the second enantiomer arising from the centrosymmetric nature of the space group.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1107/S1600536801007437
Related URLs:
ePrint ID: 19456
Date :
Date Event
1 June 2001Published
Date Deposited: 15 Feb 2006
Last Modified: 16 Apr 2017 23:02
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/19456

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