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Palladium-catalysed nucleophilic release of allylic amines from a phenolic resin

Palladium-catalysed nucleophilic release of allylic amines from a phenolic resin
Palladium-catalysed nucleophilic release of allylic amines from a phenolic resin
2 circle Allylic alcohols were coupled to phenolic polystyrene resin under Mitsunobu conditions to provide substituted allyl ethers. which underwent efficient nucleophilic cleavage by 1 degrees and 2 degrees amines in the presence of catalytic palladium to afford allylic amines.
solid-phase synthesis, organic-synthesis, combinatorial chemistry, linkers
0040-4039
8227-8230
Fisher, M.
1ba6a9e9-9021-4c95-8423-4f04c52b6f9e
Brown, R. C. D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Fisher, M.
1ba6a9e9-9021-4c95-8423-4f04c52b6f9e
Brown, R. C. D.
21ce697a-7c3a-480e-919f-429a3d8550f5

Fisher, M. and Brown, R. C. D. (2001) Palladium-catalysed nucleophilic release of allylic amines from a phenolic resin. Tetrahedron Letters, 42 (46), 8227-8230. (doi:10.1016/S0040-4039(01)01739-7).

Record type: Article

Abstract

2 circle Allylic alcohols were coupled to phenolic polystyrene resin under Mitsunobu conditions to provide substituted allyl ethers. which underwent efficient nucleophilic cleavage by 1 degrees and 2 degrees amines in the presence of catalytic palladium to afford allylic amines.

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More information

Published date: 12 November 2001
Keywords: solid-phase synthesis, organic-synthesis, combinatorial chemistry, linkers

Identifiers

Local EPrints ID: 19477
URI: http://eprints.soton.ac.uk/id/eprint/19477
ISSN: 0040-4039
PURE UUID: 9d20aab0-8a1e-41ab-89dd-012a1982b47a
ORCID for R. C. D. Brown: ORCID iD orcid.org/0000-0003-0156-7087

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 20 Jul 2019 01:16

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