Calixpyrroles II
Calixpyrroles II
This review article is the second in a series covering advances in the synthetic and molecular recognition chemistry of calixpyrrole macrocycles (meso-octasubstituted porphyrinogens). Significant progress has been made in the last three years in the use of calix[4]pyrroles as redox-active or optical sensors for anions. This period has also been marked by a number of preparative advances, including the synthesis of N-confused calix[4]pyrroles, the synthesis of extended cavity calix[4]pyrroles, and the synthesis of 'higher order' or 'expanded' calix[n]pyrroles (n > 4).
calixpyrrole, anion binding, porphyrinogen, sensors, macrocycles, anion-binding agents, molecular recognition, calixpyrroles, complexation, receptors, interface, pyrrole, cavity, ion
57-102
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Anzenbacher, Pavel
2637c1d6-7379-493a-9028-e565363722d4
Sessler, Jonathan L.
d793ea76-a3a2-4ce1-a8d5-aca7d3307fbe
1 November 2001
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Anzenbacher, Pavel
2637c1d6-7379-493a-9028-e565363722d4
Sessler, Jonathan L.
d793ea76-a3a2-4ce1-a8d5-aca7d3307fbe
Abstract
This review article is the second in a series covering advances in the synthetic and molecular recognition chemistry of calixpyrrole macrocycles (meso-octasubstituted porphyrinogens). Significant progress has been made in the last three years in the use of calix[4]pyrroles as redox-active or optical sensors for anions. This period has also been marked by a number of preparative advances, including the synthesis of N-confused calix[4]pyrroles, the synthesis of extended cavity calix[4]pyrroles, and the synthesis of 'higher order' or 'expanded' calix[n]pyrroles (n > 4).
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Published date: 1 November 2001
Keywords:
calixpyrrole, anion binding, porphyrinogen, sensors, macrocycles, anion-binding agents, molecular recognition, calixpyrroles, complexation, receptors, interface, pyrrole, cavity, ion
Identifiers
Local EPrints ID: 19484
URI: http://eprints.soton.ac.uk/id/eprint/19484
ISSN: 0010-8545
PURE UUID: 42bdc506-335f-4bdb-96ed-48b43399f8d2
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Date deposited: 15 Feb 2006
Last modified: 16 Mar 2024 03:16
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Author:
Philip A. Gale
Author:
Pavel Anzenbacher
Author:
Jonathan L. Sessler
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