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Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes

Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes
Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes
In the solid state, diesters of pyridine-2,6-dicarboxylic acid assemble into edge-to-edge, front-to-back associated tapes involving a novel triple supramolecular contact consisting of one N-pyridine***H-C-pyridine and two C=O***H-C-pyridine interactions. This intermolecular contact is robust, proving insensitive to additional interactions involving the side arms, and is also observed when the orientation of the pyridine core is reversed.
intermolecular interactions, hydrogen-bonds, complexes, chemistry, synthons, halogen
1466-8033
170-173
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Golden, Christopher A.
4aba9a97-2608-4c85-b24e-9ea106f4c4f8
Gomm, John R.
69e9f7f7-4d81-481f-bebe-6be074bc4a45
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Merckel, Daniel A.S.
3ba91499-9f0c-453f-a443-72f7ae8ad701
Oszer, Mustafa E.
4c03ee36-3cc8-4a3d-8168-083f18070de9
Parker, Robert A.
02cd9420-f342-4d0f-ba25-63296845ff43
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Golden, Christopher A.
4aba9a97-2608-4c85-b24e-9ea106f4c4f8
Gomm, John R.
69e9f7f7-4d81-481f-bebe-6be074bc4a45
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Merckel, Daniel A.S.
3ba91499-9f0c-453f-a443-72f7ae8ad701
Oszer, Mustafa E.
4c03ee36-3cc8-4a3d-8168-083f18070de9
Parker, Robert A.
02cd9420-f342-4d0f-ba25-63296845ff43

Grossel, Martin C., Golden, Christopher A., Gomm, John R., Horton, Peter N., Merckel, Daniel A.S., Oszer, Mustafa E. and Parker, Robert A. (2001) Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes. CrystEngComm, 3, 170-173. (doi:10.1039/b107221h).

Record type: Article

Abstract

In the solid state, diesters of pyridine-2,6-dicarboxylic acid assemble into edge-to-edge, front-to-back associated tapes involving a novel triple supramolecular contact consisting of one N-pyridine***H-C-pyridine and two C=O***H-C-pyridine interactions. This intermolecular contact is robust, proving insensitive to additional interactions involving the side arms, and is also observed when the orientation of the pyridine core is reversed.

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More information

Published date: 2001
Keywords: intermolecular interactions, hydrogen-bonds, complexes, chemistry, synthons, halogen

Identifiers

Local EPrints ID: 19497
URI: http://eprints.soton.ac.uk/id/eprint/19497
ISSN: 1466-8033
PURE UUID: 9922aa93-6a01-4a31-8af2-15d414b8a1c9
ORCID for Martin C. Grossel: ORCID iD orcid.org/0000-0001-7469-6854
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 06 Jun 2018 13:09

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Contributors

Author: Christopher A. Golden
Author: John R. Gomm
Author: Peter N. Horton ORCID iD
Author: Daniel A.S. Merckel
Author: Mustafa E. Oszer
Author: Robert A. Parker

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