Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes


Grossel, Martin C., Golden, Christopher A., Gomm, John R., Horton, Peter N., Merckel, Daniel A.S., Oszer, Mustafa E. and Parker, Robert A. (2001) Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes CrystEngComm, 3, pp. 170-173. (doi:10.1039/b107221h).

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Description/Abstract

In the solid state, diesters of pyridine-2,6-dicarboxylic acid assemble into edge-to-edge, front-to-back associated tapes involving a novel triple supramolecular contact consisting of one N-pyridine***H-C-pyridine and two C=O***H-C-pyridine interactions. This intermolecular contact is robust, proving insensitive to additional interactions involving the side arms, and is also observed when the orientation of the pyridine core is reversed.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b107221h
ISSNs: 1466-8033 (print)
Keywords: intermolecular interactions, hydrogen-bonds, complexes, chemistry, synthons, halogen
Subjects:
ePrint ID: 19497
Date :
Date Event
2001Published
Date Deposited: 15 Feb 2006
Last Modified: 16 Apr 2017 23:02
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/19497

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