Grossel, Martin C., Golden, Christopher A., Gomm, John R., Horton, Peter N., Merckel, Daniel A.S., Oszer, Mustafa E. and Parker, Robert A.
Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes
CrystEngComm, 3, . (doi:10.1039/b107221h).
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In the solid state, diesters of pyridine-2,6-dicarboxylic acid assemble into edge-to-edge, front-to-back associated tapes involving a novel triple supramolecular contact consisting of one N-pyridine***H-C-pyridine and two C=O***H-C-pyridine interactions. This intermolecular contact is robust, proving insensitive to additional interactions involving the side arms, and is also observed when the orientation of the pyridine core is reversed.
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