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Rational design of open-framework coordination solids - Synthesis and structure of Co-5(OH)(2){1,2,4,5-(O2C)(4)C6H2}(2)(H2O)(4) • xH(2)O

Rational design of open-framework coordination solids - Synthesis and structure of Co-5(OH)(2){1,2,4,5-(O2C)(4)C6H2}(2)(H2O)(4) • xH(2)O
Rational design of open-framework coordination solids - Synthesis and structure of Co-5(OH)(2){1,2,4,5-(O2C)(4)C6H2}(2)(H2O)(4) • xH(2)O
A strategy for preparing open-framework coordination solids by hydrothermal synthesis has been developed and tested by the synthesis of a new porous cobalt carboxylate which can be dehydrated by heating to give a material with coordinatively unsaturated metal ions.
synthesis design, cobalt, carboxylate ligands, mesoporous materials cobalt phosphate, metal, catalysts, carboxylate, micropores, oxidation, complexes, reduction, polymer, binding
1434-1948
2739-2741
Gutschke, Siegfried O.H.
586d420c-5050-43ae-9acc-238890e72511
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Powell, Annie K.
84c3aa9f-b469-489c-a4d7-264c4ec39e44
Wood, Paul T.
e6981f20-68c2-4263-bbe4-ff15eb205424
Gutschke, Siegfried O.H.
586d420c-5050-43ae-9acc-238890e72511
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Powell, Annie K.
84c3aa9f-b469-489c-a4d7-264c4ec39e44
Wood, Paul T.
e6981f20-68c2-4263-bbe4-ff15eb205424

Gutschke, Siegfried O.H., Price, Daniel J., Powell, Annie K. and Wood, Paul T. (2001) Rational design of open-framework coordination solids - Synthesis and structure of Co-5(OH)(2){1,2,4,5-(O2C)(4)C6H2}(2)(H2O)(4) • xH(2)O. European Journal of Inorganic Chemistry, (11), 2739-2741. (doi:10.1002/1099-0682(200111)2001:11<2739::AID-EJIC2739>3.0.CO;2-1).

Record type: Article

Abstract

A strategy for preparing open-framework coordination solids by hydrothermal synthesis has been developed and tested by the synthesis of a new porous cobalt carboxylate which can be dehydrated by heating to give a material with coordinatively unsaturated metal ions.

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More information

Published date: 1 November 2001
Keywords: synthesis design, cobalt, carboxylate ligands, mesoporous materials cobalt phosphate, metal, catalysts, carboxylate, micropores, oxidation, complexes, reduction, polymer, binding

Identifiers

Local EPrints ID: 19499
URI: http://eprints.soton.ac.uk/id/eprint/19499
ISSN: 1434-1948
PURE UUID: aa697b0f-2d20-47d2-98eb-8cd86b9ac061

Catalogue record

Date deposited: 16 Feb 2006
Last modified: 15 Jul 2019 19:27

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