A new cascade radical reaction for the synthesis of biaryls and triaryls from benzyl iodoaryl ethers


Harrowven, D. C., Nunn, M. I. T., Newman, N. A. and Fenwick, D. R. (2001) A new cascade radical reaction for the synthesis of biaryls and triaryls from benzyl iodoaryl ethers Tetrahedron Letters, 42, (5), pp. 961-964. (doi:10.1016/S0040-4039(00)02111-0).

Download

Full text not available from this repository.

Description/Abstract

The paper describes a new method of synthesizing biaryls and triaryls through an intramolecular ipso-substitution reaction initiated by the addition of an aryl radical to a benzyl ether. A tandem variant of the reaction has also been demonstrated. A short synthesis of isoaucuparin 27, a natural product found in the sapwood tissue of Sorbus aucuparia, is also described.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/S0040-4039(00)02111-0
ISSNs: 0040-4039 (print)
Keywords: radicals and radical reactions, natural products, aromatic chemistry, cascade reactionscondensed thiophenes
Subjects:
ePrint ID: 19507
Date :
Date Event
29 January 2001Published
Date Deposited: 14 Feb 2006
Last Modified: 16 Apr 2017 23:02
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/19507

Actions (login required)

View Item View Item