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A new cascade radical reaction for the synthesis of biaryls and triaryls from benzyl iodoaryl ethers

Harrowven, D. C., Nunn, M. I. T., Newman, N. A. and Fenwick, D. R. (2001) A new cascade radical reaction for the synthesis of biaryls and triaryls from benzyl iodoaryl ethers Tetrahedron Letters, 42, (5), pp. 961-964. (doi:10.1016/S0040-4039(00)02111-0).

Record type: Article

Abstract

The paper describes a new method of synthesizing biaryls and triaryls through an intramolecular ipso-substitution reaction initiated by the addition of an aryl radical to a benzyl ether. A tandem variant of the reaction has also been demonstrated. A short synthesis of isoaucuparin 27, a natural product found in the sapwood tissue of Sorbus aucuparia, is also described.

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More information

Published date: 29 January 2001
Keywords: radicals and radical reactions, natural products, aromatic chemistry, cascade reactionscondensed thiophenes

Identifiers

Local EPrints ID: 19507
URI: http://eprints.soton.ac.uk/id/eprint/19507
ISSN: 0040-4039
PURE UUID: 6e0f9cfd-8f1f-4fd6-a2c3-d70be7ebdabc

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 17 Jul 2017 16:31

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Contributors

Author: D. C. Harrowven
Author: M. I. T. Nunn
Author: N. A. Newman
Author: D. R. Fenwick

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