Intramolecular radical additions to quinolines
Intramolecular radical additions to quinolines
This paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines, was observed (implicating the so called oxidative tin hydride pathway).
radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationtert-butylmercury halides, condensed thiophenes, cyclizations, butylation, bu3snh
2907-2910
Harrowven, D. C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Sutton, B. J.
dce4566b-0de3-45bd-9c44-56887eb86f55
Coulton, S.
9d74c362-5867-4bef-ad9f-d3b819f042ca
9 April 2001
Harrowven, D. C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Sutton, B. J.
dce4566b-0de3-45bd-9c44-56887eb86f55
Coulton, S.
9d74c362-5867-4bef-ad9f-d3b819f042ca
Harrowven, D. C., Sutton, B. J. and Coulton, S.
(2001)
Intramolecular radical additions to quinolines.
Tetrahedron Letters, 42 (15), .
(doi:10.1016/S0040-4039(01)00321-5).
Abstract
This paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines, was observed (implicating the so called oxidative tin hydride pathway).
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Published date: 9 April 2001
Keywords:
radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationtert-butylmercury halides, condensed thiophenes, cyclizations, butylation, bu3snh
Identifiers
Local EPrints ID: 19509
URI: http://eprints.soton.ac.uk/id/eprint/19509
ISSN: 0040-4039
PURE UUID: b0a43ddb-3e3f-43f9-8f66-bbc131a43182
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Date deposited: 14 Feb 2006
Last modified: 16 Mar 2024 02:46
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Author:
B. J. Sutton
Author:
S. Coulton
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