Intramolecular radical additions to quinolines

Harrowven, D. C., Sutton, B. J. and Coulton, S. (2001) Intramolecular radical additions to quinolines Tetrahedron Letters, 42, (15), pp. 2907-2910. (doi:10.1016/S0040-4039(01)00321-5).


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This paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines, was observed (implicating the so called oxidative tin hydride pathway).

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/S0040-4039(01)00321-5
ISSNs: 0040-4039 (print)
Keywords: radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationtert-butylmercury halides, condensed thiophenes, cyclizations, butylation, bu3snh
ePrint ID: 19509
Date :
Date Event
9 April 2001Published
Date Deposited: 14 Feb 2006
Last Modified: 16 Apr 2017 23:02
Further Information:Google Scholar

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