A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement
A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement
In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.
chemistry
369-370
Khan, T.
4f420fa9-3a2b-4206-adb5-95fd7795f797
Skabara, P. J.
a4ac32fc-e003-45f7-ab89-d28eb2027bed
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
2001
Khan, T.
4f420fa9-3a2b-4206-adb5-95fd7795f797
Skabara, P. J.
a4ac32fc-e003-45f7-ab89-d28eb2027bed
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Khan, T., Skabara, P. J., Coles, S. J. and Hursthouse, M. B.
(2001)
A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement.
Chemical Communications, (4), .
(doi:10.1039/b009550h).
Abstract
In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.
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Published date: 2001
Keywords:
chemistry
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Local EPrints ID: 19531
URI: http://eprints.soton.ac.uk/id/eprint/19531
ISSN: 1359-7345
PURE UUID: 0acaff2e-65a1-4cd7-afcb-caff99b0e3a2
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Date deposited: 14 Feb 2006
Last modified: 16 Mar 2024 03:05
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Author:
T. Khan
Author:
P. J. Skabara
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