A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement


Khan, T., Skabara, P. J., Coles, S. J. and Hursthouse, M. B. (2001) A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement Chemical Communications, (4), pp. 369-370. (doi:10.1039/b009550h).

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Description/Abstract

In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b009550h
ISSNs: 1359-7345 (print)
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Keywords: chemistry
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ePrint ID: 19531
Date :
Date Event
2001Published
Date Deposited: 14 Feb 2006
Last Modified: 16 Apr 2017 23:01
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/19531

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