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Synthesis and properties of the first series of mixed thioether/telluroether macrocycles

Synthesis and properties of the first series of mixed thioether/telluroether macrocycles
Synthesis and properties of the first series of mixed thioether/telluroether macrocycles
The preparations of the first examples of mixed thioether/telluroether macrocycles, [9]aneS(2)Te (1,4-dithia-7-telluracyclononane), [11]aneS(2)Te (1,4-dithia-8-telluracycloundecane), [12]aneS(2)Te (1,5-dithia-9-telluracyclododecane) and [14]aneS(3)Te (1,4,7-trithia-11-telluracyclotetradecane) via a 'disguised dilution' method are described, together with the crystal structure of [Ag([11]aneS(2)Te)]BF4 which serves to authenticate the macrocyclic ligand.
ditelluroether complexes, crystal-structures, ligands
1359-7345
427-428
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Orchard, S. D.
90cbc344-8d53-406f-acf4-ad93cef1ddae
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Orchard, S. D.
90cbc344-8d53-406f-acf4-ad93cef1ddae
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037

Levason, W., Orchard, S. D. and Reid, G. (2001) Synthesis and properties of the first series of mixed thioether/telluroether macrocycles. Chemical Communications, (5), 427-428. (doi:10.1039/b008370o).

Record type: Article

Abstract

The preparations of the first examples of mixed thioether/telluroether macrocycles, [9]aneS(2)Te (1,4-dithia-7-telluracyclononane), [11]aneS(2)Te (1,4-dithia-8-telluracycloundecane), [12]aneS(2)Te (1,5-dithia-9-telluracyclododecane) and [14]aneS(3)Te (1,4,7-trithia-11-telluracyclotetradecane) via a 'disguised dilution' method are described, together with the crystal structure of [Ag([11]aneS(2)Te)]BF4 which serves to authenticate the macrocyclic ligand.

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More information

Published date: 2001
Keywords: ditelluroether complexes, crystal-structures, ligands

Identifiers

Local EPrints ID: 19547
URI: http://eprints.soton.ac.uk/id/eprint/19547
ISSN: 1359-7345
PURE UUID: 490f25e4-128b-4053-b59e-06fe049b95ce
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for G. Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 16 Mar 2024 02:43

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Contributors

Author: W. Levason ORCID iD
Author: S. D. Orchard
Author: G. Reid ORCID iD

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