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Scandium, yttrium and lanthanum nitrate complexes of tertiary arsine oxides: synthesis and multinuclear spectroscopic studies. X-ray structures of [M(Me3AsO)6](NO3)3 (M=Sc or Y), [Sc(Ph3AsO)3(NO3)2]NO3, [M?(Ph3AsO)4(NO3)2]NO3 (M?=Y or La) and [La(Ph3AsO)2(EtOH)(NO3)3]

Levason, W., Patel, B., Popham, M. C., Reid, G. and Webster, M. (2001) Scandium, yttrium and lanthanum nitrate complexes of tertiary arsine oxides: synthesis and multinuclear spectroscopic studies. X-ray structures of [M(Me3AsO)6](NO3)3 (M=Sc or Y), [Sc(Ph3AsO)3(NO3)2]NO3, [M?(Ph3AsO)4(NO3)2]NO3 (M?=Y or La) and [La(Ph3AsO)2(EtOH)(NO3)3] Polyhedron, 20, (21), pp. 2711-2720. (doi:10.1016/S0277-5387(01)00889-0).

Record type: Article

Abstract

The reaction of Ph3AsO with Sc(NO3)(3). 5H(2)O, Y(NO3)(3). 6H(2)O or La(NO3)(3). 6H(2)O in acetone gave [Sc(Ph3AsO)(2)(NO3)(3)], [Y(Ph3AsO)(4)(NO3)(2)]NO3, [La(Ph3AsO)(4)(NO3)(2)]NO3, and [La(Ph3AsO)(3)(NO3)(3)], whilst from ethanol solution [Sc(Ph3AsO)(3)(NO3)(2)]NO3, [Y(Ph3AsO)(2)(EtOH)(NO3)(3)] and [La(Ph3AsO)(2)(EtOH)(NO3)(3)] were produced. Similar reactions using Me3AsO produced [M(Me3AsO)(6)](NO3)(3) (M = SC, Y or La) and [La(Me3AsO)(2)(H2O)(NO3)(3)]. All complexes were characterised by analysis, IR and H-1, Sc-45 or Y-89 NMR spectroscopy, and conductance measurements. The solution speciation and interconversions of the Sc and Y complexes have been probed by Sc-45 and Y-89 NMR spectroscopy. X-Ray crystal structures are reported for the 6-coordinate [M(Me3AsO)(6)](NO3)(3) (M = Sc or Y), seven-coordinate [Sc(Ph3AsO)(3)(NO3)(2)]NO3, eight-coordinate [M"(Ph3AsO)(4)(NO3)(2)]NO3 (M" = Y or La), and nine-coordinate [La(Ph3AsO)(2)(EtOH)(NO3)(3)].

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More information

Published date: 30 September 2001
Keywords: scandium, yttrium, lanthanum, nmr spectroscopy, x-ray structures

Identifiers

Local EPrints ID: 19548
URI: http://eprints.soton.ac.uk/id/eprint/19548
ISSN: 0277-5387
PURE UUID: 84687c0b-67fe-4cc3-b6f0-e13b176fc9bb
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971

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Date deposited: 13 Feb 2006
Last modified: 17 Jul 2017 16:31

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Contributors

Author: W. Levason ORCID iD
Author: B. Patel
Author: M. C. Popham
Author: G. Reid
Author: M. Webster

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