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Macrocyclic and polydentate thio- and seleno-ether ligand complexes of the p-block elements

Macrocyclic and polydentate thio- and seleno-ether ligand complexes of the p-block elements
Macrocyclic and polydentate thio- and seleno-ether ligand complexes of the p-block elements
The diverse structures exhibited by complexes of p-block (Group 13-15) halides with acyclic and macrocyclic thio-, seleno-, and telluro-ethers are described. Examples range from six-coordinate monomers through to one-, two- or three-dimensional network infinite polymers with structural motifs often very different to those found with d-block elements.
crown thioether chemistry, crystal-structures, molecular-structure, tin(iv) halides, magnetic-resonance, bismuth(iii), coordination, hypervalent, lead(ii), rings
1477-9226
2953-2960
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037

Levason, William and Reid, Gillian (2001) Macrocyclic and polydentate thio- and seleno-ether ligand complexes of the p-block elements. Dalton Transactions, (20), 2953-2960. (doi:10.1039/b105973b).

Record type: Article

Abstract

The diverse structures exhibited by complexes of p-block (Group 13-15) halides with acyclic and macrocyclic thio-, seleno-, and telluro-ethers are described. Examples range from six-coordinate monomers through to one-, two- or three-dimensional network infinite polymers with structural motifs often very different to those found with d-block elements.

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More information

Published date: 2001
Additional Information: Royal Society of Chemistry
Keywords: crown thioether chemistry, crystal-structures, molecular-structure, tin(iv) halides, magnetic-resonance, bismuth(iii), coordination, hypervalent, lead(ii), rings

Identifiers

Local EPrints ID: 19550
URI: http://eprints.soton.ac.uk/id/eprint/19550
ISSN: 1477-9226
PURE UUID: 1fd75524-9985-4a82-b211-1d3d498f748f
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 10 Dec 2019 01:59

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