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High-resolution 1H NMR in the solid state using symmetry-based pulse sequences

High-resolution 1H NMR in the solid state using symmetry-based pulse sequences
High-resolution 1H NMR in the solid state using symmetry-based pulse sequences
We demonstrate new rotor synchronised pulse sequences for obtaining high-resolution H-1 NMR spectra in the presence of fast magic angle spinning (MAS). The new sequences exploit selection rules generated by appropriate synchronisation of the radio-frequency (rf) field modulations and the sample rotation. We show preliminary results demonstrating the feasibility of high-resolution proton NMR spectroscopy in the presence of fast MAS, and also demonstrate the resolution of H-1-C-13 J-couplings in the solid state.
nuclear-magnetic-resonance, angle-spinning nmr, rotating solids, h-1-nmr, tensors, cramps
0009-2614
142-148
Madhu, P.K.
d3e7accb-343e-4ad0-9ef2-56e505202bbb
Zhao, X.
c32d0dd5-3ac6-4c9c-b41e-95baa08c7472
Levitt, M.H.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3
Madhu, P.K.
d3e7accb-343e-4ad0-9ef2-56e505202bbb
Zhao, X.
c32d0dd5-3ac6-4c9c-b41e-95baa08c7472
Levitt, M.H.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3

Madhu, P.K., Zhao, X. and Levitt, M.H. (2001) High-resolution 1H NMR in the solid state using symmetry-based pulse sequences. Chemical Physics Letters, 346 (1-2), 142-148. (doi:10.1016/S0009-2614(01)00876-4).

Record type: Article

Abstract

We demonstrate new rotor synchronised pulse sequences for obtaining high-resolution H-1 NMR spectra in the presence of fast magic angle spinning (MAS). The new sequences exploit selection rules generated by appropriate synchronisation of the radio-frequency (rf) field modulations and the sample rotation. We show preliminary results demonstrating the feasibility of high-resolution proton NMR spectroscopy in the presence of fast MAS, and also demonstrate the resolution of H-1-C-13 J-couplings in the solid state.

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More information

Published date: 28 September 2001
Keywords: nuclear-magnetic-resonance, angle-spinning nmr, rotating solids, h-1-nmr, tensors, cramps

Identifiers

Local EPrints ID: 19571
URI: http://eprints.soton.ac.uk/id/eprint/19571
ISSN: 0009-2614
PURE UUID: 5231583c-d85a-4b7e-9fcd-45cbc4239a60
ORCID for M.H. Levitt: ORCID iD orcid.org/0000-0001-9878-1180

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 20 Jul 2019 01:06

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Contributors

Author: P.K. Madhu
Author: X. Zhao
Author: M.H. Levitt ORCID iD

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