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The infrared spectra of products of tantalum and ruthenium reactions with fluorine isolated in solid argon

The infrared spectra of products of tantalum and ruthenium reactions with fluorine isolated in solid argon
The infrared spectra of products of tantalum and ruthenium reactions with fluorine isolated in solid argon
The IR spectra of the products formed when molecular fluorine was passed over tantalum and ruthenium heated to 100-1100 degreesC and isolated in inert matrices at 12 K were studied. In the Ta + F-2 system, bands of (TaF5)(3), TaF5, and TaF4 were observed. In the Ru + F-2 system, the major reaction product was monomeric ruthenium pentafluoride. The structures of metal fluorides of various compositions are discussed.
high-temperatures
0036-0244
1312-1318
Osin, S.B.
95aa37e8-c0d5-4496-87a5-ab0cf5060e04
Davlyatshin, D.I.
720e3d58-c5f0-4e43-8e81-c715b90e476a
Ogden, J.S.
5488b4c4-8119-46c9-a647-928c95804efd
Osin, S.B.
95aa37e8-c0d5-4496-87a5-ab0cf5060e04
Davlyatshin, D.I.
720e3d58-c5f0-4e43-8e81-c715b90e476a
Ogden, J.S.
5488b4c4-8119-46c9-a647-928c95804efd

Osin, S.B., Davlyatshin, D.I. and Ogden, J.S. (2001) The infrared spectra of products of tantalum and ruthenium reactions with fluorine isolated in solid argon. Russian Journal of Physical Chemistry A, 75 (8), 1312-1318.

Record type: Article

Abstract

The IR spectra of the products formed when molecular fluorine was passed over tantalum and ruthenium heated to 100-1100 degreesC and isolated in inert matrices at 12 K were studied. In the Ta + F-2 system, bands of (TaF5)(3), TaF5, and TaF4 were observed. In the Ru + F-2 system, the major reaction product was monomeric ruthenium pentafluoride. The structures of metal fluorides of various compositions are discussed.

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Published date: 1 August 2001
Keywords: high-temperatures

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Local EPrints ID: 19585
URI: http://eprints.soton.ac.uk/id/eprint/19585
ISSN: 0036-0244
PURE UUID: 6416bd55-79f1-4aa6-bd2d-1b8a35938b48

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Date deposited: 14 Feb 2006
Last modified: 12 Mar 2018 17:31

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