The University of Southampton
University of Southampton Institutional Repository

Infrared spectra of the products of interaction of tungsten and molybdenum with fluorine isolated in solid argon

Infrared spectra of the products of interaction of tungsten and molybdenum with fluorine isolated in solid argon
Infrared spectra of the products of interaction of tungsten and molybdenum with fluorine isolated in solid argon
The IR spectra of the products formed when molecular fluorine passed over molybdenum and tungsten (heated to 100-1100 degreesC) and isolated in inert matrices at 12 K were recorded. In the W + F-2 system, the major product was tungsten hexafluoride. For the Mo + F-2 system, bands of MoF6, MoOF4, (MoF5)(3), MoF5, MoF4, and, possibly, MoF3 were identified. The spectra were interpreted with the use of thermodynamic calculations of the equilibrium composition of the gas phase at various temperatures. The structure of metal fluorides of different compositions is discussed.
force-field, molecules, hexafluoride
0036-0244
237-245
Osin, S.B.
95aa37e8-c0d5-4496-87a5-ab0cf5060e04
Davlyatshin, D.I.
720e3d58-c5f0-4e43-8e81-c715b90e476a
Ogden, J.S.
d022e70d-b424-4100-9517-64a46486dd8c
Osin, S.B.
95aa37e8-c0d5-4496-87a5-ab0cf5060e04
Davlyatshin, D.I.
720e3d58-c5f0-4e43-8e81-c715b90e476a
Ogden, J.S.
d022e70d-b424-4100-9517-64a46486dd8c

Osin, S.B., Davlyatshin, D.I. and Ogden, J.S. (2001) Infrared spectra of the products of interaction of tungsten and molybdenum with fluorine isolated in solid argon. Journal of Physical Chemistry A, 75 (2), 237-245.

Record type: Article

Abstract

The IR spectra of the products formed when molecular fluorine passed over molybdenum and tungsten (heated to 100-1100 degreesC) and isolated in inert matrices at 12 K were recorded. In the W + F-2 system, the major product was tungsten hexafluoride. For the Mo + F-2 system, bands of MoF6, MoOF4, (MoF5)(3), MoF5, MoF4, and, possibly, MoF3 were identified. The spectra were interpreted with the use of thermodynamic calculations of the equilibrium composition of the gas phase at various temperatures. The structure of metal fluorides of different compositions is discussed.

Full text not available from this repository.

More information

Published date: 1 February 2001
Keywords: force-field, molecules, hexafluoride

Identifiers

Local EPrints ID: 19586
URI: http://eprints.soton.ac.uk/id/eprint/19586
ISSN: 0036-0244
PURE UUID: e704e026-bd10-4b93-bce1-53a1148328b5

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 17 Jul 2017 16:31

Export record

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×