1,4 additions with lithium bis(methylenecyclopropyl)cuprate

Peron, G., Norton, D., Kitteringham, J. and Kilburn, J. D. (2001) 1,4 additions with lithium bis(methylenecyclopropyl)cuprate Tetrahedron Letters, 42, (2), pp. 347-349. (doi:10.1016/S0040-4039(00)01957-2).


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Addition of lithium bis(methylenecyclopropyl) cuprate to alpha,beta -unsaturated ketones provides an efficient route to methylenecyclopropyl ketones which on treatment with TiCl4 give a range of cyclised products.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/S0040-4039(00)01957-2
ISSNs: 0040-4039 (print)
Keywords: methylenecyclopropane, cuprate, lewis acid methylenecyclopropane derivatives, radical cyclizations, aldehydes, ketones
ePrint ID: 19592
Date :
Date Event
8 January 2001Published
Date Deposited: 14 Feb 2006
Last Modified: 16 Apr 2017 23:01
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/19592

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