1,4 additions with lithium bis(methylenecyclopropyl)cuprate

Peron, G., Norton, D., Kitteringham, J. and Kilburn, J. D. (2001) 1,4 additions with lithium bis(methylenecyclopropyl)cuprate. Tetrahedron Letters, 42 (2), 347-349. (doi:10.1016/S0040-4039(00)01957-2).

Record type: Article

Abstract

Addition of lithium bis(methylenecyclopropyl) cuprate to alpha,beta -unsaturated ketones provides an efficient route to methylenecyclopropyl ketones which on treatment with TiCl4 give a range of cyclised products.

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Published date: 8 January 2001

Keywords: methylenecyclopropane, cuprate, lewis acid methylenecyclopropane derivatives, radical cyclizations, aldehydes, ketones

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Identifiers

Local EPrints ID: 19592

URI: http://eprints.soton.ac.uk/id/eprint/19592

DOI: doi:10.1016/S0040-4039(00)01957-2

ISSN: 0040-4039

PURE UUID: 0f025d42-646c-4619-ba8d-c40e4017e193

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Date deposited: 14 Feb 2006

Last modified: 15 Mar 2024 06:17

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Contributors

Author: G. Peron

Author: D. Norton

Author: J. Kitteringham

Author: J. D. Kilburn

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