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Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate

Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate
Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate
Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase I of composition [Cu(Py2C6H12)(3)(NO3)(2)].2[Cu(Py2C6H12)(2)(H2O)(NO3)].2(NO3). EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition [Cu-2(Py2C6H12)(4)(H2O)(2)]. (NO3)(4). (Py2C6H12). (EtOH).2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent.
supramolecular, crystal engineering polymer, channels, 1, 3-bis(4-pyridyl)propane, framework, cations, ligands, solids
319-328
Plater, M.John
8c02f0d2-f901-4dbd-9636-bc6599571806
Foreman, Mark R.St.J.
5bebb161-7d54-42e2-bf3c-89c9f6dc2c6d
Gelbrich, Thomas
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Plater, M.John
8c02f0d2-f901-4dbd-9636-bc6599571806
Foreman, Mark R.St.J.
5bebb161-7d54-42e2-bf3c-89c9f6dc2c6d
Gelbrich, Thomas
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Plater, M.John, Foreman, Mark R.St.J., Gelbrich, Thomas and Hursthouse, Michael B. (2001) Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate. Crystal Engineering, 4 (4), 319-328. (doi:10.1016/S1463-0184(01)00024-7).

Record type: Article

Abstract

Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase I of composition [Cu(Py2C6H12)(3)(NO3)(2)].2[Cu(Py2C6H12)(2)(H2O)(NO3)].2(NO3). EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition [Cu-2(Py2C6H12)(4)(H2O)(2)]. (NO3)(4). (Py2C6H12). (EtOH).2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent.

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More information

Published date: 1 December 2001
Keywords: supramolecular, crystal engineering polymer, channels, 1, 3-bis(4-pyridyl)propane, framework, cations, ligands, solids

Identifiers

Local EPrints ID: 19599
URI: http://eprints.soton.ac.uk/id/eprint/19599
PURE UUID: abe359ce-5796-4b52-a227-21771c630b44

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Date deposited: 14 Feb 2006
Last modified: 15 Jul 2019 19:26

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