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One-dimensional structures of nickel(II) and cobalt(II) coordination complexes { ML2(H2O)(2) I center dot L center dot H2O (ClO4)(2)} (M = Co or Ni; L=1,3-bis(4-pyridyl)propane)

One-dimensional structures of nickel(II) and cobalt(II) coordination complexes { ML2(H2O)(2) I center dot L center dot H2O (ClO4)(2)} (M = Co or Ni; L=1,3-bis(4-pyridyl)propane)
One-dimensional structures of nickel(II) and cobalt(II) coordination complexes { ML2(H2O)(2) I center dot L center dot H2O (ClO4)(2)} (M = Co or Ni; L=1,3-bis(4-pyridyl)propane)
Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO4)(2) or Ni(II)(ClO4)(2) gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain an array of non-coordinated ligands are hydrogen bonded at each end to the ligated water molecules.
crystal structure, nickel complexes, cobalt complexes, one-dimensional complexespolymers, channels, framework, cations, solids
0020-1693
171-174
Plater, M. John
b5fd2be8-1818-470e-b12a-64e7601175a3
Foreman, M.R.St.J
4b7b1221-752e-4950-b86e-a679dfa5856d
Gelbrich, Thomas
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Plater, M. John
b5fd2be8-1818-470e-b12a-64e7601175a3
Foreman, M.R.St.J
4b7b1221-752e-4950-b86e-a679dfa5856d
Gelbrich, Thomas
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Plater, M. John, Foreman, M.R.St.J, Gelbrich, Thomas and Hursthouse, Michael B. (2001) One-dimensional structures of nickel(II) and cobalt(II) coordination complexes { ML2(H2O)(2) I center dot L center dot H2O (ClO4)(2)} (M = Co or Ni; L=1,3-bis(4-pyridyl)propane). Inorganica Chimica Acta, 318 (1-2), 171-174. (doi:10.1016/S0020-1693(01)00406-6).

Record type: Article

Abstract

Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO4)(2) or Ni(II)(ClO4)(2) gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain an array of non-coordinated ligands are hydrogen bonded at each end to the ligated water molecules.

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Published date: 18 June 2001
Keywords: crystal structure, nickel complexes, cobalt complexes, one-dimensional complexespolymers, channels, framework, cations, solids

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Local EPrints ID: 19600
URI: http://eprints.soton.ac.uk/id/eprint/19600
ISSN: 0020-1693
PURE UUID: bef27fba-48fa-4adf-afd4-1f06a8571993

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Date deposited: 14 Feb 2006
Last modified: 15 Jul 2019 19:26

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Author: M. John Plater
Author: M.R.St.J Foreman
Author: Thomas Gelbrich

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