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The first molecular charge transfer salt containing proton channels

The first molecular charge transfer salt containing proton channels
The first molecular charge transfer salt containing proton channels
We report the first molecular charge transfer salt containing channels of H3O+/H2O within its lattice; it is formulated ?"(BEDT-TTF)(4)[(H3O)Cr(C2O4)(3)](2)[(H3O)(2)(18-crown-6)]. 5H(2)O [BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene], deduced from the crystal structure and C=C and C-S bond lengths and Raman stretching frequencies.
bedt-ttf salts, superconductors
1359-7345
1462-1463
Rashid, Samina
b8e8f6e2-0e59-411c-ac79-d629820aadd8
Turner, Scott S.
dff25cc2-54a4-4c11-9621-fbe854931843
Day, Peter
2eda54f4-9e67-4134-98a1-7fdf7c91be22
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Firth, Steven
23130861-b2b2-45df-8052-aa27c1b0a463
Clark, Robin J.H.
8d98d858-ec31-4dd4-8557-7e6530b2bf02
Rashid, Samina
b8e8f6e2-0e59-411c-ac79-d629820aadd8
Turner, Scott S.
dff25cc2-54a4-4c11-9621-fbe854931843
Day, Peter
2eda54f4-9e67-4134-98a1-7fdf7c91be22
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Firth, Steven
23130861-b2b2-45df-8052-aa27c1b0a463
Clark, Robin J.H.
8d98d858-ec31-4dd4-8557-7e6530b2bf02

Rashid, Samina, Turner, Scott S., Day, Peter, Light, Mark E., Hursthouse, Michael B., Firth, Steven and Clark, Robin J.H. (2001) The first molecular charge transfer salt containing proton channels. Chemical Communications, (16), 1462-1463. (doi:10.1039/b103877j).

Record type: Article

Abstract

We report the first molecular charge transfer salt containing channels of H3O+/H2O within its lattice; it is formulated ?"(BEDT-TTF)(4)[(H3O)Cr(C2O4)(3)](2)[(H3O)(2)(18-crown-6)]. 5H(2)O [BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene], deduced from the crystal structure and C=C and C-S bond lengths and Raman stretching frequencies.

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More information

Published date: 21 August 2001
Keywords: bedt-ttf salts, superconductors

Identifiers

Local EPrints ID: 19606
URI: http://eprints.soton.ac.uk/id/eprint/19606
ISSN: 1359-7345
PURE UUID: 3e5ef1ad-d4f8-4f5e-b8bc-7cf7f5436850
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 03 Dec 2019 01:55

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