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(BEDT-TTF)4[(H3O)Cr(C2O4)3]CH2Cl2: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt

(BEDT-TTF)4[(H3O)Cr(C2O4)3]CH2Cl2: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt
(BEDT-TTF)4[(H3O)Cr(C2O4)3]CH2Cl2: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt
The new charge-transfer salt beta "-(BEDT-TTF)(4)[(H3O)Cr(C2O4)(3)]S, where BEDT-TTF = bis(ethylenedithio)tetrathiaful valene and S = CH2Cl2, has a broad metal-insulator transition at approximately 150 K. This differs from similar salts in the BEDT-TTF tris(oxalato) metalate Series, notably the superconducting materials with S = PhCN and the salt with S = C5H5N, which has a sharp metal-insulator transition.
superconductor, ions
0020-1669
5304-5306
Rashid, Samina
b8e8f6e2-0e59-411c-ac79-d629820aadd8
Turner, Scott S.
dff25cc2-54a4-4c11-9621-fbe854931843
Le Pevelen, Delphine
3ed0a8b1-9521-43ea-8f02-27fb1f957737
Day, Peter
2eda54f4-9e67-4134-98a1-7fdf7c91be22
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Firth, Steven
23130861-b2b2-45df-8052-aa27c1b0a463
Clark, Robin J. H.
76cca979-fd6e-4f67-9216-63c741d35d8d
Rashid, Samina
b8e8f6e2-0e59-411c-ac79-d629820aadd8
Turner, Scott S.
dff25cc2-54a4-4c11-9621-fbe854931843
Le Pevelen, Delphine
3ed0a8b1-9521-43ea-8f02-27fb1f957737
Day, Peter
2eda54f4-9e67-4134-98a1-7fdf7c91be22
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Firth, Steven
23130861-b2b2-45df-8052-aa27c1b0a463
Clark, Robin J. H.
76cca979-fd6e-4f67-9216-63c741d35d8d

Rashid, Samina, Turner, Scott S., Le Pevelen, Delphine, Day, Peter, Light, Mark E., Hursthouse, Michael B., Firth, Steven and Clark, Robin J. H. (2001) (BEDT-TTF)4[(H3O)Cr(C2O4)3]CH2Cl2: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt. Inorganic Chemistry, 40 (20), 5304-5306. (doi:10.1021/ic010484f).

Record type: Article

Abstract

The new charge-transfer salt beta "-(BEDT-TTF)(4)[(H3O)Cr(C2O4)(3)]S, where BEDT-TTF = bis(ethylenedithio)tetrathiaful valene and S = CH2Cl2, has a broad metal-insulator transition at approximately 150 K. This differs from similar salts in the BEDT-TTF tris(oxalato) metalate Series, notably the superconducting materials with S = PhCN and the salt with S = C5H5N, which has a sharp metal-insulator transition.

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More information

Published date: 24 September 2001
Keywords: superconductor, ions

Identifiers

Local EPrints ID: 19608
URI: http://eprints.soton.ac.uk/id/eprint/19608
ISSN: 0020-1669
PURE UUID: 0a16e304-c3cf-441b-86a1-55611c2a303d
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 05 Nov 2019 01:56

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