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Synthesis and spectroscopic studies of novel ?-diketonate copper(I) compounds and solid state structure of tetravinylsilane tetrakis copper(I) 1,1,1,5,5,5-hexafluoroacetylacetonate (TVST [Cu] hfac)

Synthesis and spectroscopic studies of novel ?-diketonate copper(I) compounds and solid state structure of tetravinylsilane tetrakis copper(I) 1,1,1,5,5,5-hexafluoroacetylacetonate (TVST [Cu] hfac)
Synthesis and spectroscopic studies of novel ?-diketonate copper(I) compounds and solid state structure of tetravinylsilane tetrakis copper(I) 1,1,1,5,5,5-hexafluoroacetylacetonate (TVST [Cu] hfac)
Reactions between tetraalkene silanes SiR4 (R = vinyl and allyl), copper(I) oxide, and 1, 1, 1, 5,5,5-hexafluoroacetylacetonate (hfac) gave novel multicoordinated ?-diketonate copper(I) Lewis base ligand complexes. The synthesis and spectroscopic data of tetravinylsilane biscopper(I)hfac complex (TVSB[Cu]hfac) (1), tetravinylsilane tetrakiscopper(I)hfac (TVST-[Cu]hfac) (2), and tetrallylsilane triscopper(I)hfac complex (TASTri[Cu]hfac) (3) are presented, and the structural characterization of tetravinylsilane tetrakiscopper(I)hfac (TVST[Cu]hfac) (2) is reported.
chemical-vapor-deposition, metal, metallization, precursors, films
0276-7333
4001-4005
Rozenberg, Gregor G.
ca87c412-81b7-4cf5-bc68-002490f4ad52
Steinke, Joachim H. G.
2ebe33db-c66f-44c9-815d-9a43f9f3b487
Gelbrich, Thomas
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Rozenberg, Gregor G.
ca87c412-81b7-4cf5-bc68-002490f4ad52
Steinke, Joachim H. G.
2ebe33db-c66f-44c9-815d-9a43f9f3b487
Gelbrich, Thomas
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Rozenberg, Gregor G., Steinke, Joachim H. G., Gelbrich, Thomas and Hursthouse, Michael B. (2001) Synthesis and spectroscopic studies of novel ?-diketonate copper(I) compounds and solid state structure of tetravinylsilane tetrakis copper(I) 1,1,1,5,5,5-hexafluoroacetylacetonate (TVST [Cu] hfac). Organometallics, 20 (19), 4001-4005. (doi:10.1021/om010268e).

Record type: Article

Abstract

Reactions between tetraalkene silanes SiR4 (R = vinyl and allyl), copper(I) oxide, and 1, 1, 1, 5,5,5-hexafluoroacetylacetonate (hfac) gave novel multicoordinated ?-diketonate copper(I) Lewis base ligand complexes. The synthesis and spectroscopic data of tetravinylsilane biscopper(I)hfac complex (TVSB[Cu]hfac) (1), tetravinylsilane tetrakiscopper(I)hfac (TVST-[Cu]hfac) (2), and tetrallylsilane triscopper(I)hfac complex (TASTri[Cu]hfac) (3) are presented, and the structural characterization of tetravinylsilane tetrakiscopper(I)hfac (TVST[Cu]hfac) (2) is reported.

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More information

Published date: 17 September 2001
Keywords: chemical-vapor-deposition, metal, metallization, precursors, films

Identifiers

Local EPrints ID: 19611
URI: http://eprints.soton.ac.uk/id/eprint/19611
ISSN: 0276-7333
PURE UUID: 0bcf116c-5af0-4316-939e-22329567aad6

Catalogue record

Date deposited: 14 Feb 2006
Last modified: 15 Jul 2019 19:26

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