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Palladium-catalysed synthesis of imidates, thioimidates and amidines from aryl halides

Palladium-catalysed synthesis of imidates, thioimidates and amidines from aryl halides
Palladium-catalysed synthesis of imidates, thioimidates and amidines from aryl halides
Palladium-catalysed coupling between aryl- or heteroaryl-bromides, alkoxides, aryloxides or thioalkoxides. and isocyanides gives aryl-imidates and -thioimidates in high yield. Amidines can be synthesised in a one-pot procedure via imidates.
imidate, thioimidate, amidine, palladium homogeneous catalysis multicomponent reactionscarbonylation, derivatives
0040-4039
6191-6194
Saluste, C. Gustaf
409f2bf4-c2cf-4c57-ae7c-f46039e96fd3
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Furber, Mark
efd9d188-1c08-48f8-b800-9410411862d1
Saluste, C. Gustaf
409f2bf4-c2cf-4c57-ae7c-f46039e96fd3
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Furber, Mark
efd9d188-1c08-48f8-b800-9410411862d1

Saluste, C. Gustaf, Whitby, Richard J. and Furber, Mark (2001) Palladium-catalysed synthesis of imidates, thioimidates and amidines from aryl halides. Tetrahedron Letters, 42 (35), 6191-6194. (doi:10.1016/S0040-4039(01)01201-1).

Record type: Article

Abstract

Palladium-catalysed coupling between aryl- or heteroaryl-bromides, alkoxides, aryloxides or thioalkoxides. and isocyanides gives aryl-imidates and -thioimidates in high yield. Amidines can be synthesised in a one-pot procedure via imidates.

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More information

Published date: 27 August 2001
Keywords: imidate, thioimidate, amidine, palladium homogeneous catalysis multicomponent reactionscarbonylation, derivatives
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Identifiers

Local EPrints ID: 19615
URI: http://eprints.soton.ac.uk/id/eprint/19615
DOI: doi:10.1016/S0040-4039(01)01201-1
ISSN: 0040-4039
PURE UUID: e1ea53a2-dcb2-4286-a051-52b9c050427e
ORCID for Richard J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

Catalogue record

Date deposited: 13 Feb 2006
Last modified: 16 Mar 2024 02:33

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Contributors

Author: C. Gustaf Saluste
Author: Richard J. Whitby ORCID iD
Author: Mark Furber

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