Synthesis and crystal structures of two new (Te,N,) type hybrid organotellurium ligands
Synthesis and crystal structures of two new (Te,N,) type hybrid organotellurium ligands
The reaction of N-(2-chloroethyl)benzamide and N-[3-bromopropyl]phthalimide with ArTe- Na+ generated in situ by borohydride reduction of Ar2Te2, has resulted in N-[2-(4-methoxyphenyltelluro)ethyl] benzamide (L-1) and N-[2-(4-methoxyphenyl telluro)propyl] phthalimide (L-2) respectively, which are potentially (Te, N)-type ligands. Their NMR (H-1 and C-13) spectra are characteristic and single crystal structures are solved. The Te-C(alkyl) distance [2.140(8)/2.151(4) Angstrom] is longer than Te-C(aryl) distance [2.107(8)/2.128(5)Å].
hybrid organotellurium ligands, platinum(ii) complexes, palladium(ii), mercury(ii), l-1, n-phthalimide, diorganotellurides, chemistry, tellurium, chloride, ligation
339-341
Singh, A. K.
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Sooriyakumar, J.
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Kadarkaraisamy, M.
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Drake, J. E.
dee0cd4d-79bf-4024-ad9c-d61bfaf9216b
Hursthouse, M. B.
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Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Butcher, R. J.
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1 August 2001
Singh, A. K.
c8db0073-98b0-436c-8247-1cdda740765c
Sooriyakumar, J.
f150a0af-bd9f-4214-a7e6-642dd582729b
Kadarkaraisamy, M.
4736f5c7-a996-45f3-871c-51dbb977d1d3
Drake, J. E.
dee0cd4d-79bf-4024-ad9c-d61bfaf9216b
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Butcher, R. J.
19b6c6d8-eada-423f-969f-310959612e58
Singh, A. K., Sooriyakumar, J., Kadarkaraisamy, M., Drake, J. E., Hursthouse, M. B., Light, M. E. and Butcher, R. J.
(2001)
Synthesis and crystal structures of two new (Te,N,) type hybrid organotellurium ligands.
Journal of Chemical Research, (8), .
Abstract
The reaction of N-(2-chloroethyl)benzamide and N-[3-bromopropyl]phthalimide with ArTe- Na+ generated in situ by borohydride reduction of Ar2Te2, has resulted in N-[2-(4-methoxyphenyltelluro)ethyl] benzamide (L-1) and N-[2-(4-methoxyphenyl telluro)propyl] phthalimide (L-2) respectively, which are potentially (Te, N)-type ligands. Their NMR (H-1 and C-13) spectra are characteristic and single crystal structures are solved. The Te-C(alkyl) distance [2.140(8)/2.151(4) Angstrom] is longer than Te-C(aryl) distance [2.107(8)/2.128(5)Å].
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Published date: 1 August 2001
Keywords:
hybrid organotellurium ligands, platinum(ii) complexes, palladium(ii), mercury(ii), l-1, n-phthalimide, diorganotellurides, chemistry, tellurium, chloride, ligation
Identifiers
Local EPrints ID: 19620
URI: http://eprints.soton.ac.uk/id/eprint/19620
ISSN: 0308-2342
PURE UUID: 41c995ff-c4d3-4d7a-a602-80aa71f13515
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Date deposited: 13 Feb 2006
Last modified: 09 Jan 2022 02:59
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Contributors
Author:
A. K. Singh
Author:
J. Sooriyakumar
Author:
M. Kadarkaraisamy
Author:
J. E. Drake
Author:
R. J. Butcher
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