The University of Southampton
University of Southampton Institutional Repository

Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands

Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands
Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecholboryl (BO2C6Cl4) ligand are reported. Crystallographic study of the methylcyclopentadienyl derivative (eta(5)-C5H4Me)Fe(CO)(2)BO2C6Cl4 allows comparison of structure and bonding with related complexes of the type (eta(5)-C5R5)Fe(CO)(2)B(OR)(2) and reveals that the relative orientation of (eta(5)-C5H4Me)Fe(CO)(2) and BO2C6Cl4 moieties is influenced by intramolecular C---H...O hydrogen bonding. Additionally, an alternative route to catecholboryl complexes from dilithiocatechol is reported.
boryl, boron, iron, manganese, hydrogen bond, substitution, structural-characterization, hydrogen-bond, functionalization, chemistry, alkanes, hydroborations, hydrocarbons, activation, boranes
0022-328X
9-14
Aldridge, S.
a8a450f9-3ecc-4105-815d-62b02f7c5a02
Calder, R.J.
e12a0178-2a5b-4dee-9c0d-2ab6e6e3d470
Baghurst, R.E.
87666b68-6f79-4bc7-b56f-fb41a1ed5959
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Aldridge, S.
a8a450f9-3ecc-4105-815d-62b02f7c5a02
Calder, R.J.
e12a0178-2a5b-4dee-9c0d-2ab6e6e3d470
Baghurst, R.E.
87666b68-6f79-4bc7-b56f-fb41a1ed5959
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Aldridge, S., Calder, R.J., Baghurst, R.E., Light, M.E. and Hursthouse, M.B. (2002) Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands. Journal of Organometallic Chemistry, 649 (1), 9-14. (doi:10.1016/S0022-328X(01)01427-9).

Record type: Article

Abstract

The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecholboryl (BO2C6Cl4) ligand are reported. Crystallographic study of the methylcyclopentadienyl derivative (eta(5)-C5H4Me)Fe(CO)(2)BO2C6Cl4 allows comparison of structure and bonding with related complexes of the type (eta(5)-C5R5)Fe(CO)(2)B(OR)(2) and reveals that the relative orientation of (eta(5)-C5H4Me)Fe(CO)(2) and BO2C6Cl4 moieties is influenced by intramolecular C---H...O hydrogen bonding. Additionally, an alternative route to catecholboryl complexes from dilithiocatechol is reported.

Full text not available from this repository.

More information

Published date: 15 April 2002
Keywords: boryl, boron, iron, manganese, hydrogen bond, substitution, structural-characterization, hydrogen-bond, functionalization, chemistry, alkanes, hydroborations, hydrocarbons, activation, boranes

Identifiers

Local EPrints ID: 19651
URI: http://eprints.soton.ac.uk/id/eprint/19651
ISSN: 0022-328X
PURE UUID: e60a40f7-13b7-45eb-b645-d522d9ff9929
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 18 Feb 2021 16:52

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×