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Linking of metal centres through boryl ligands: synthesis, spectroscopic and structural characterisation of symmetrically bridged boryl complexes

Linking of metal centres through boryl ligands: synthesis, spectroscopic and structural characterisation of symmetrically bridged boryl complexes
Linking of metal centres through boryl ligands: synthesis, spectroscopic and structural characterisation of symmetrically bridged boryl complexes
Dinuclear species containing iron centres linked via various bridging boryl ligands have been synthesised and a combination of crystallographic, computational and spectroscopic (Mössbauer, IR, Raman) techniques have been used to probe the bonding in these complexes.
bond-dissociation energies, organometallic compounds, transition-metals, functionalization, diboration, chemistry, alkanes, iron, hydroboration, hydrocarbons
1472-7773
2020-2026
Aldridge, Simon
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Calder, Richard J.
eb1fe8d2-ab06-45fd-84ab-0285dfec28ef
Rossin, Andrea
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Dickinson, Anthony A.
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Willock, David J.
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Jones, Cameron
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Evans, David J.
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Steed, Jonathan W.
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Light, Mark E.
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Coles, Simon J.
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Hursthouse, Michael B.
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Aldridge, Simon
de66448a-0f63-4b8b-ac55-f78dcd4830ea
Calder, Richard J.
eb1fe8d2-ab06-45fd-84ab-0285dfec28ef
Rossin, Andrea
67cb4de3-4c58-4f7d-bbd2-f7ece6e2f458
Dickinson, Anthony A.
b3daf9d2-a910-41f4-b542-1185f2439328
Willock, David J.
d17cca22-472d-4d1b-91a3-e412008a9ca4
Jones, Cameron
80277af4-ec6c-453a-a18c-0be82a3d18d5
Evans, David J.
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Steed, Jonathan W.
97a5b8f6-b374-454d-a0b4-0bcaf37aa962
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Aldridge, Simon, Calder, Richard J., Rossin, Andrea, Dickinson, Anthony A., Willock, David J., Jones, Cameron, Evans, David J., Steed, Jonathan W., Light, Mark E., Coles, Simon J. and Hursthouse, Michael B. (2002) Linking of metal centres through boryl ligands: synthesis, spectroscopic and structural characterisation of symmetrically bridged boryl complexes. Journal of the Chemical Society, Dalton Transactions, (9), 2020-2026. (doi:10.1039/b200695m).

Record type: Article

Abstract

Dinuclear species containing iron centres linked via various bridging boryl ligands have been synthesised and a combination of crystallographic, computational and spectroscopic (Mössbauer, IR, Raman) techniques have been used to probe the bonding in these complexes.

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More information

Published date: 2002
Keywords: bond-dissociation energies, organometallic compounds, transition-metals, functionalization, diboration, chemistry, alkanes, iron, hydroboration, hydrocarbons

Identifiers

Local EPrints ID: 19653
URI: http://eprints.soton.ac.uk/id/eprint/19653
ISSN: 1472-7773
PURE UUID: ebf7742e-eb66-450e-bd5a-768868d51ef2
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 18 Feb 2021 16:52

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Contributors

Author: Simon Aldridge
Author: Richard J. Calder
Author: Andrea Rossin
Author: Anthony A. Dickinson
Author: David J. Willock
Author: Cameron Jones
Author: David J. Evans
Author: Jonathan W. Steed
Author: Mark E. Light ORCID iD
Author: Simon J. Coles ORCID iD

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