Allen, David W., Berridge, Rory, Bricklebank, Neil, Cerrada, Elena, Light, Mark E., Hursthouse, Michael B., Laguna, Mariano, Moreno, Ana and Skabara, Peter J. (2002) A new family of sulfur-rich ligands based on the dmit system: synthesis and metal complexation of 4-4'-covalently bridged bis(2-thioxo-1,3-dithiol-5-thiolato) units. Journal of the Chemical Society, Dalton Transactions, (13), 2654-2659. (doi:10.1039/b201615j).
Abstract
The synthesis of a new series of sulfur-rich ligands is reported. These compounds, which are related to the dmit(2-) (2-thioxo-1,3-dithiol-4,5-dithiolato) structure, comprise two 2-thioxo-1,3-dithiol-5-thiolato units linked by a bridging unit at the 4-position of the heterocycle via a dithioether spacer unit. Complexation reactions have been carried out on a variety of metal centres; dialkyl tin and gold(I) derivatives have been isolated and fully characterised. The X-ray crystal structure of an octahedral Ni(II) complex, involving two coordinating pyridine molecules, is presented.
This record has no associated files available for download.
More information
Identifiers
Catalogue record
Export record
Altmetrics
Contributors
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.