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Hypervalent intramolecular coordination in main group chemistry: a template synthesis and crystal structure of an ortho-oximinoarylphosphonium salt

Hypervalent intramolecular coordination in main group chemistry: a template synthesis and crystal structure of an ortho-oximinoarylphosphonium salt
Hypervalent intramolecular coordination in main group chemistry: a template synthesis and crystal structure of an ortho-oximinoarylphosphonium salt
The nickel(II)-catalysed reaction of triphenylphosphine with the oxime of ortho-bromoacetophenone gives an ortho-oximinoarylphosphonium salt, which shows a hypervalent intramolecular coordinative interaction between the oximino-nitrogen and the phosphonium centre.
hypervalent intramolecular coordination, ortho-oximinoarylphosphonium salt, arylphosphonium salts, tertiary phosphines, catalyzed formation, phosphorus, arsonium, silicon
0308-2342
537-539
Allen, D.W.
568c774f-914a-45a3-9593-352d7e9913eb
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Allen, D.W.
568c774f-914a-45a3-9593-352d7e9913eb
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Allen, D.W., Light, M.E. and Hursthouse, M.B. (2002) Hypervalent intramolecular coordination in main group chemistry: a template synthesis and crystal structure of an ortho-oximinoarylphosphonium salt. Journal of Chemical Research, (11), 537-539.

Record type: Article

Abstract

The nickel(II)-catalysed reaction of triphenylphosphine with the oxime of ortho-bromoacetophenone gives an ortho-oximinoarylphosphonium salt, which shows a hypervalent intramolecular coordinative interaction between the oximino-nitrogen and the phosphonium centre.

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More information

Published date: 1 November 2002
Keywords: hypervalent intramolecular coordination, ortho-oximinoarylphosphonium salt, arylphosphonium salts, tertiary phosphines, catalyzed formation, phosphorus, arsonium, silicon

Identifiers

Local EPrints ID: 19655
URI: http://eprints.soton.ac.uk/id/eprint/19655
ISSN: 0308-2342
PURE UUID: ec4db0a2-4298-49f1-936b-94ac718425db
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 18 Feb 2021 16:52

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