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Synthesis of enantiopure 3-azabicyclo [3.3.0] octen-7-one derivatives via intramolecular Pauson-Khand cycloaddition reaction using tri-O-acetyl-D-glucal as starting material

Synthesis of enantiopure 3-azabicyclo [3.3.0] octen-7-one derivatives via intramolecular Pauson-Khand cycloaddition reaction using tri-O-acetyl-D-glucal as starting material
Synthesis of enantiopure 3-azabicyclo [3.3.0] octen-7-one derivatives via intramolecular Pauson-Khand cycloaddition reaction using tri-O-acetyl-D-glucal as starting material
Some N-substituted-3-azabicyclo[3.3.0]octen-7-one derivatives have been synthesized in an enantiomerically pure form starting from tri-O-acetyl-D-glucal via intramolecular Pauson-Khand (IPK) cycloaddition.
(-)-alpha-kainic acid, ethylene equivalents, carbene complexes, vinyl esters
0022-3263
3506-3509
Areces, Pilar
3a8ae816-4a9d-404b-a7a0-d5e69617d474
Durán, M. Ángeles
9524ad3e-3a05-4ec0-badb-c2d8aca023fe
Plumet, Joaquín
01d4818d-7490-40a2-a88f-773d272aa776
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Areces, Pilar
3a8ae816-4a9d-404b-a7a0-d5e69617d474
Durán, M. Ángeles
9524ad3e-3a05-4ec0-badb-c2d8aca023fe
Plumet, Joaquín
01d4818d-7490-40a2-a88f-773d272aa776
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161

Areces, Pilar, Durán, M. Ángeles, Plumet, Joaquín, Hursthouse, Michael B. and Light, Mark E. (2002) Synthesis of enantiopure 3-azabicyclo [3.3.0] octen-7-one derivatives via intramolecular Pauson-Khand cycloaddition reaction using tri-O-acetyl-D-glucal as starting material. Journal of Organic Chemistry, 67 (10), 3506-3509. (doi:10.1021/jo011129+).

Record type: Article

Abstract

Some N-substituted-3-azabicyclo[3.3.0]octen-7-one derivatives have been synthesized in an enantiomerically pure form starting from tri-O-acetyl-D-glucal via intramolecular Pauson-Khand (IPK) cycloaddition.

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More information

Published date: 2002
Keywords: (-)-alpha-kainic acid, ethylene equivalents, carbene complexes, vinyl esters

Identifiers

Local EPrints ID: 19657
URI: http://eprints.soton.ac.uk/id/eprint/19657
ISSN: 0022-3263
PURE UUID: 9f229d40-debf-4e3f-8ebb-d459f2eaba1d
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 18 Feb 2021 16:52

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