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The reaction of C60F20 with anthracene: formation of an oxidised-anthracene 1 : 1 complex

The reaction of C60F20 with anthracene: formation of an oxidised-anthracene 1 : 1 complex
The reaction of C60F20 with anthracene: formation of an oxidised-anthracene 1 : 1 complex
The reaction of C60F20 ("Saturnene") with anthracene yields a white 1 : 1 cycloadduct (1) in which two oxygen atoms have inserted into the anthracene framework due to fullerene-catalysed oxidation; the F-19 NMR spectrum of the product shows evidence of through-cage homoconjugation.
fullerene, derivatives, c-70
227-233
Avent, Anthony G.
6fe5d51d-5f31-454f-938a-ec91c840f2ce
Boltalina, Olga V.
7fefd47c-6427-4d51-8d9f-e1b116daad8c
Street, Joan M.
186366c0-692b-4236-bb93-e2a3b6e9395c
Taylor, Roger
16cca243-6646-4c6f-a563-321c2b1bb0f6
Troshin, Pavel A.
2b947e1c-315c-4b0b-9842-6cd6acdfc85c
Wei, Xian-Wen
76b952ea-9f76-41de-be81-91f46652c927
Avent, Anthony G.
6fe5d51d-5f31-454f-938a-ec91c840f2ce
Boltalina, Olga V.
7fefd47c-6427-4d51-8d9f-e1b116daad8c
Street, Joan M.
186366c0-692b-4236-bb93-e2a3b6e9395c
Taylor, Roger
16cca243-6646-4c6f-a563-321c2b1bb0f6
Troshin, Pavel A.
2b947e1c-315c-4b0b-9842-6cd6acdfc85c
Wei, Xian-Wen
76b952ea-9f76-41de-be81-91f46652c927

Avent, Anthony G., Boltalina, Olga V., Street, Joan M., Taylor, Roger, Troshin, Pavel A. and Wei, Xian-Wen (2002) The reaction of C60F20 with anthracene: formation of an oxidised-anthracene 1 : 1 complex. Fullerenes, Nanotubes, and Carbon Nanostructures, 10 (3), 227-233. (doi:10.1081/FST-120014737).

Record type: Article

Abstract

The reaction of C60F20 ("Saturnene") with anthracene yields a white 1 : 1 cycloadduct (1) in which two oxygen atoms have inserted into the anthracene framework due to fullerene-catalysed oxidation; the F-19 NMR spectrum of the product shows evidence of through-cage homoconjugation.

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More information

Published date: 2002
Keywords: fullerene, derivatives, c-70

Identifiers

Local EPrints ID: 19660
URI: http://eprints.soton.ac.uk/id/eprint/19660
PURE UUID: 80bcf808-d528-49ff-895e-f9e9d6cb2558

Catalogue record

Date deposited: 15 Feb 2006
Last modified: 15 Jul 2019 19:26

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