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Susceptibility of a heterogeneous catalyst, Rh/?-alumina, to rapid structural change by exposure to NO

Susceptibility of a heterogeneous catalyst, Rh/?-alumina, to rapid structural change by exposure to NO
Susceptibility of a heterogeneous catalyst, Rh/?-alumina, to rapid structural change by exposure to NO
Metal particles in a Rh/?-Al2O3 catalyst of differing particle size are oxidised by NO/He within 5 seconds at 313 K; rapid, highly exothermic dissociative chemisorption of NO is the initial step.
rhodium, co, chemisorption, reduction, exafs, size
1359-7345
304-305
Campbell, Tom
57689594-8890-4064-b0e0-3eae0099a6b0
Dent, Andrew J.
24c2a218-cb0e-4193-af0b-3ff1dc42b552
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Fiddy, Steven G.
f6c255cf-6aa1-4798-85ca-1a2ccdaa1186
Newton, Mark A.
73aab2af-4641-47f3-89ad-3b7d3026164f
Turin, Sandra
6691348e-e3e2-4afb-8384-131a363a07d0
Campbell, Tom
57689594-8890-4064-b0e0-3eae0099a6b0
Dent, Andrew J.
24c2a218-cb0e-4193-af0b-3ff1dc42b552
Diaz-Moreno, Sofia
4e280df3-7f62-4280-8058-2803c740ae00
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Fiddy, Steven G.
f6c255cf-6aa1-4798-85ca-1a2ccdaa1186
Newton, Mark A.
73aab2af-4641-47f3-89ad-3b7d3026164f
Turin, Sandra
6691348e-e3e2-4afb-8384-131a363a07d0

Campbell, Tom, Dent, Andrew J., Diaz-Moreno, Sofia, Evans, John, Fiddy, Steven G., Newton, Mark A. and Turin, Sandra (2002) Susceptibility of a heterogeneous catalyst, Rh/?-alumina, to rapid structural change by exposure to NO. Chemical Communications, (4), 304-305. (doi:10.1039/b106846f).

Record type: Article

Abstract

Metal particles in a Rh/?-Al2O3 catalyst of differing particle size are oxidised by NO/He within 5 seconds at 313 K; rapid, highly exothermic dissociative chemisorption of NO is the initial step.

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More information

Published date: 2002
Keywords: rhodium, co, chemisorption, reduction, exafs, size

Identifiers

Local EPrints ID: 19692
URI: http://eprints.soton.ac.uk/id/eprint/19692
ISSN: 1359-7345
PURE UUID: a2849b14-2deb-4a1e-b129-1faf1a43451d

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 05 Oct 2018 12:04

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