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Synthesis and structural characterisation of stable pyridine- and phosphine-functionalised N-heterocyclic carbenes

Synthesis and structural characterisation of stable pyridine- and phosphine-functionalised N-heterocyclic carbenes
Synthesis and structural characterisation of stable pyridine- and phosphine-functionalised N-heterocyclic carbenes
Stable, uncoordinated {1-[2-(6-trimethylsilyl)pyridyl] 3-[( 2,6-diisopropyl)phenyl] imidazol-2-ylidene}, I, and {1-[?-(diphenylphosphino)ethyl]-3-[(2,6-diisopropyl) phenyl] imidazol-2-ylidene}, II, have been synthesised; in the solid state they adopt a conformation with the lone pairs in a mutually anti arrangement.
complexes, equilibrium, palladium
1359-7345
482-483
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Winston, Scott
d7cc4b37-c1c0-4c11-b210-c172d21fc544
Gelbrich, Thomas
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Tooze, Robert P.
9461ecde-9da0-42c6-a17f-6387bd8c5a7b
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Winston, Scott
d7cc4b37-c1c0-4c11-b210-c172d21fc544
Gelbrich, Thomas
42309d69-eaf1-4bb7-ba2e-db61f338e370
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Tooze, Robert P.
9461ecde-9da0-42c6-a17f-6387bd8c5a7b

Danopoulos, Andreas A., Winston, Scott, Gelbrich, Thomas, Hursthouse, Michael B. and Tooze, Robert P. (2002) Synthesis and structural characterisation of stable pyridine- and phosphine-functionalised N-heterocyclic carbenes. Chemical Communications, (5), 482-483. (doi:10.1039/b111659b).

Record type: Article

Abstract

Stable, uncoordinated {1-[2-(6-trimethylsilyl)pyridyl] 3-[( 2,6-diisopropyl)phenyl] imidazol-2-ylidene}, I, and {1-[?-(diphenylphosphino)ethyl]-3-[(2,6-diisopropyl) phenyl] imidazol-2-ylidene}, II, have been synthesised; in the solid state they adopt a conformation with the lone pairs in a mutually anti arrangement.

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More information

Published date: 2002
Keywords: complexes, equilibrium, palladium

Identifiers

Local EPrints ID: 19714
URI: http://eprints.soton.ac.uk/id/eprint/19714
ISSN: 1359-7345
PURE UUID: 73874c52-0637-4bd5-8bc8-2034cbdfeb96

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 15 Jul 2019 19:26

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