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Stable N-functionalised 'pincer' bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies

Stable N-functionalised 'pincer' bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies
Stable N-functionalised 'pincer' bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies
Deprotonation of 2,6-bis(arylimidazolium)pyridine dibromide with KN(SiMe3)(2) gave thermally stable 2,6-bis(arylimidazol-2-ylidene)pyridine, which was further used to prepare ruthenium 'pincer' complexes; the latter show catalytic activity in transfer hydrogenation of carbonyl compounds.
heterocyclic carbenes, palladium, alkenes, silver, pd
1359-7345
1376-1377
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Winston, Scott
d7cc4b37-c1c0-4c11-b210-c172d21fc544
Motherwell, William B.
77559985-75b3-4d25-9a26-9a93c520a871
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Winston, Scott
d7cc4b37-c1c0-4c11-b210-c172d21fc544
Motherwell, William B.
77559985-75b3-4d25-9a26-9a93c520a871

Danopoulos, Andreas A., Winston, Scott and Motherwell, William B. (2002) Stable N-functionalised 'pincer' bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies. Chemical Communications, 2002 (13), 1376-1377. (doi:10.1039/b202814j).

Record type: Article

Abstract

Deprotonation of 2,6-bis(arylimidazolium)pyridine dibromide with KN(SiMe3)(2) gave thermally stable 2,6-bis(arylimidazol-2-ylidene)pyridine, which was further used to prepare ruthenium 'pincer' complexes; the latter show catalytic activity in transfer hydrogenation of carbonyl compounds.

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More information

Published date: 2002
Keywords: heterocyclic carbenes, palladium, alkenes, silver, pd

Identifiers

Local EPrints ID: 19716
URI: http://eprints.soton.ac.uk/id/eprint/19716
ISSN: 1359-7345
PURE UUID: 92d8038a-7e03-4115-8719-02391ed5dbb8

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 14 Sep 2021 19:29

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