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Radical cyclisations to arenes for the synthesis of phenanthrenes

Radical cyclisations to arenes for the synthesis of phenanthrenes
Radical cyclisations to arenes for the synthesis of phenanthrenes
6-exo/endo-Trig intramolecular additions of aryl radicals to electron-rich, unsubstituted and electron-deficient arenes have all been shown to proceed efficiently to give the corresponding phenanthrenes in high yield.
radicals and radical reactions, aromatic chemistry, phenanthrenes ipso substitution-reactions, aryl migration, biaryls, carbon, cyclization, toddaquinoline, silicon, tin, methylenecycloalkanes, regiochemistry
0040-4039
3185-3187
Harrowven, D. C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Nunn, M. I. T.
b8208d55-5e1b-45fb-a1cc-8e1df72d6b2d
Fenwick, D. R.
6021f20e-6a22-41c6-bc2d-67c4ea2f8d59
Harrowven, D. C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Nunn, M. I. T.
b8208d55-5e1b-45fb-a1cc-8e1df72d6b2d
Fenwick, D. R.
6021f20e-6a22-41c6-bc2d-67c4ea2f8d59

Harrowven, D. C., Nunn, M. I. T. and Fenwick, D. R. (2002) Radical cyclisations to arenes for the synthesis of phenanthrenes. Tetrahedron Letters, 43 (17), 3185-3187. (doi:10.1016/S0040-4039(02)00505-1).

Record type: Article

Abstract

6-exo/endo-Trig intramolecular additions of aryl radicals to electron-rich, unsubstituted and electron-deficient arenes have all been shown to proceed efficiently to give the corresponding phenanthrenes in high yield.

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More information

Published date: 22 April 2002
Keywords: radicals and radical reactions, aromatic chemistry, phenanthrenes ipso substitution-reactions, aryl migration, biaryls, carbon, cyclization, toddaquinoline, silicon, tin, methylenecycloalkanes, regiochemistry

Identifiers

Local EPrints ID: 19759
URI: http://eprints.soton.ac.uk/id/eprint/19759
ISSN: 0040-4039
PURE UUID: cad22110-e5f0-434d-9419-244ceb5b8230
ORCID for D. C. Harrowven: ORCID iD orcid.org/0000-0001-6730-3573

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 09 Jan 2022 02:46

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Contributors

Author: D. C. Harrowven ORCID iD
Author: M. I. T. Nunn
Author: D. R. Fenwick

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