Radical cyclisations to arenes for the synthesis of phenanthrenes
Radical cyclisations to arenes for the synthesis of phenanthrenes
6-exo/endo-Trig intramolecular additions of aryl radicals to electron-rich, unsubstituted and electron-deficient arenes have all been shown to proceed efficiently to give the corresponding phenanthrenes in high yield.
radicals and radical reactions, aromatic chemistry, phenanthrenes
ipso substitution-reactions, aryl migration, biaryls, carbon, cyclization, toddaquinoline, silicon, tin, methylenecycloalkanes, regiochemistry
3185-3187
Harrowven, D. C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Nunn, M. I. T.
b8208d55-5e1b-45fb-a1cc-8e1df72d6b2d
Fenwick, D. R.
6021f20e-6a22-41c6-bc2d-67c4ea2f8d59
22 April 2002
Harrowven, D. C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Nunn, M. I. T.
b8208d55-5e1b-45fb-a1cc-8e1df72d6b2d
Fenwick, D. R.
6021f20e-6a22-41c6-bc2d-67c4ea2f8d59
Harrowven, D. C., Nunn, M. I. T. and Fenwick, D. R.
(2002)
Radical cyclisations to arenes for the synthesis of phenanthrenes.
Tetrahedron Letters, 43 (17), .
(doi:10.1016/S0040-4039(02)00505-1).
Abstract
6-exo/endo-Trig intramolecular additions of aryl radicals to electron-rich, unsubstituted and electron-deficient arenes have all been shown to proceed efficiently to give the corresponding phenanthrenes in high yield.
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Published date: 22 April 2002
Keywords:
radicals and radical reactions, aromatic chemistry, phenanthrenes
ipso substitution-reactions, aryl migration, biaryls, carbon, cyclization, toddaquinoline, silicon, tin, methylenecycloalkanes, regiochemistry
Identifiers
Local EPrints ID: 19759
URI: http://eprints.soton.ac.uk/id/eprint/19759
ISSN: 0040-4039
PURE UUID: cad22110-e5f0-434d-9419-244ceb5b8230
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Date deposited: 17 Feb 2006
Last modified: 16 Mar 2024 02:46
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Author:
M. I. T. Nunn
Author:
D. R. Fenwick
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