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Radical cyclisations to arenes for the synthesis of phenanthrenes

Record type: Article

6-exo/endo-Trig intramolecular additions of aryl radicals to electron-rich, unsubstituted and electron-deficient arenes have all been shown to proceed efficiently to give the corresponding phenanthrenes in high yield.

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Citation

Harrowven, D. C., Nunn, M. I. T. and Fenwick, D. R. (2002) Radical cyclisations to arenes for the synthesis of phenanthrenes Tetrahedron Letters, 43, (17), pp. 3185-3187. (doi:10.1016/S0040-4039(02)00505-1).

More information

Published date: 22 April 2002
Keywords: radicals and radical reactions, aromatic chemistry, phenanthrenes ipso substitution-reactions, aryl migration, biaryls, carbon, cyclization, toddaquinoline, silicon, tin, methylenecycloalkanes, regiochemistry

Identifiers

Local EPrints ID: 19759
URI: http://eprints.soton.ac.uk/id/eprint/19759
ISSN: 0040-4039
PURE UUID: cad22110-e5f0-434d-9419-244ceb5b8230

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 17 Jul 2017 16:30

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Contributors

Author: D. C. Harrowven
Author: M. I. T. Nunn
Author: D. R. Fenwick

University divisions


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