Radical cyclisations to arenes for the synthesis of phenanthrenes


Harrowven, D. C., Nunn, M. I. T. and Fenwick, D. R. (2002) Radical cyclisations to arenes for the synthesis of phenanthrenes Tetrahedron Letters, 43, (17), pp. 3185-3187. (doi:10.1016/S0040-4039(02)00505-1).

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Description/Abstract

6-exo/endo-Trig intramolecular additions of aryl radicals to electron-rich, unsubstituted and electron-deficient arenes have all been shown to proceed efficiently to give the corresponding phenanthrenes in high yield.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/S0040-4039(02)00505-1
ISSNs: 0040-4039 (print)
Keywords: radicals and radical reactions, aromatic chemistry, phenanthrenes ipso substitution-reactions, aryl migration, biaryls, carbon, cyclization, toddaquinoline, silicon, tin, methylenecycloalkanes, regiochemistry
Subjects:
ePrint ID: 19759
Date :
Date Event
22 April 2002Published
Date Deposited: 17 Feb 2006
Last Modified: 16 Apr 2017 23:01
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/19759

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