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Intramolecular radical additions to quinolines

Harrowven, D. C., Sutton, B. J. and Coulton, S. (2002) Intramolecular radical additions to quinolines Tetrahedron, 58, (17), pp. 3387-3400. (doi:10.1016/S0040-4020(02)00295-8).

Record type: Article


The paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines. was observed (implicating the so called oxidative tin hydride pathway).

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Published date: 22 April 2002
Keywords: radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationipso substitution-reactions, tert-butylmercury halides, pyridiniumrings, cyclization, alkaloids, pyrroles, biaryls, bu3snh, route, toddaquinoline


Local EPrints ID: 19761
ISSN: 0040-4020
PURE UUID: 969aae33-bf6c-48f0-b4ee-855d3e5daf97

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Date deposited: 17 Feb 2006
Last modified: 17 Jul 2017 16:30

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Author: D. C. Harrowven
Author: B. J. Sutton
Author: S. Coulton

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